Chemical Communications

, volume 58 , issue 63 , pages 8778-8781

C(sp³)–H Ritter amination by excitation of in situ generated iodine(iii)–BF₃ complexes

Rok Narobe ^{1, 2}

Kathiravan Murugesan ^{1, 2}

Christoph Haag ^{1, 2}

Tobias Emanuel Schirmer ^{1, 2}

Burkhard König ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

Institute of Organic Chemistry, University of Regensburg, Universitätsstraße 31, 93053, Regensburg, Germany |

Institute of Organic Chemistry, University of Regensburg, Universitätsstraße 31, Regensburg, Germany |

Publication type: Journal Article

Publication date: 2022-07-07

Royal Society of Chemistry (RSC)

Chemical Communications

scimago Q1

wos Q2

SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/d2cc03283j

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PubMed ID: 35843213

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

Visible light excitation of iodine(III)–BF3 complex enables the formation of carbocations from C(sp3)–H bonds. The complexes are generated catalytically from iodoarene, carboxylate ligand, the oxidizing agent Selectfluor, and the Lewis acid BF3. This modular catalytic system allows the formation of synthetically valuable amine derivatives without a metal- or photocatalyst.

Found

1 citation

Budnikova Yulia

DSc in Chemistry, professor

259 publications, 4 512 citations, 54 reviews

h-index: 34

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

C-H functionalization

Catalysis

Charge transfer

Chemistry of organoelement compounds

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GOST |

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GOST Copy

Narobe R. et al. C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes // Chemical Communications. 2022. Vol. 58. No. 63. pp. 8778-8781.

GOST all authors (up to 50) Copy

Narobe R., Murugesan K., Haag C., Schirmer T. E., König B. C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes // Chemical Communications. 2022. Vol. 58. No. 63. pp. 8778-8781.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/d2cc03283j

UR - https://xlink.rsc.org/?DOI=D2CC03283J

TI - C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes

T2 - Chemical Communications

AU - Narobe, Rok

AU - Murugesan, Kathiravan

AU - Haag, Christoph

AU - Schirmer, Tobias Emanuel

AU - König, Burkhard

PY - 2022

DA - 2022/07/07

PB - Royal Society of Chemistry (RSC)

SP - 8778-8781

IS - 63

VL - 58

PMID - 35843213

SN - 1359-7345

SN - 1364-548X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2022_Narobe,

author = {Rok Narobe and Kathiravan Murugesan and Christoph Haag and Tobias Emanuel Schirmer and Burkhard König},

title = {C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes},

journal = {Chemical Communications},

year = {2022},

volume = {58},

publisher = {Royal Society of Chemistry (RSC)},

month = {jul},

url = {https://xlink.rsc.org/?DOI=D2CC03283J},

number = {63},

pages = {8778--8781},

doi = {10.1039/d2cc03283j}

}

MLA

Cite this

MLA Copy

Narobe, Rok, et al. “C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes.” Chemical Communications, vol. 58, no. 63, Jul. 2022, pp. 8778-8781. https://xlink.rsc.org/?DOI=D2CC03283J.

Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

scimago Q1

wos Q2

SJR

1.037

CiteScore

7.4

Impact factor

4.2

ISSN

13597345 (Print)

1364548X (Electronic)

Profiles

Burkhard N König