Chemical Communications

, том 58 , издание 63 , страницы 8778-8781

C(sp³)–H Ritter amination by excitation of in situ generated iodine(iii)–BF₃ complexes

Rok Narobe ^{1, 2}

Kathiravan Murugesan ^{1, 2}

Christoph Haag ^{1, 2}

Tobias Emanuel Schirmer ^{1, 2}

Burkhard König ^{1, 2}

Скрыть аффилиации авторов Показать аффилиации авторов: 2 аффилиации

Institute of Organic Chemistry, University of Regensburg, Universitätsstraße 31, 93053, Regensburg, Germany |

Institute of Organic Chemistry, University of Regensburg, Universitätsstraße 31, Regensburg, Germany |

Тип публикации: Journal Article

Дата публикации: 2022-07-07

Royal Society of Chemistry (RSC)

Chemical Communications

scimago Q1

wos Q2

БС1

SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/d2cc03283j

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PubMed ID: 35843213

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Краткое описание

Visible light excitation of iodine(III)–BF3 complex enables the formation of carbocations from C(sp3)–H bonds. The complexes are generated catalytically from iodoarene, carboxylate ligand, the oxidizing agent Selectfluor, and the Lewis acid BF3. This modular catalytic system allows the formation of synthetically valuable amine derivatives without a metal- or photocatalyst.

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Институт органической и физической химии им. А.Е. Арбузова КазНЦ РАН

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Narobe R. et al. C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes // Chemical Communications. 2022. Vol. 58. No. 63. pp. 8778-8781.

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Narobe R., Murugesan K., Haag C., Schirmer T. E., König B. C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes // Chemical Communications. 2022. Vol. 58. No. 63. pp. 8778-8781.

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TY - JOUR

DO - 10.1039/d2cc03283j

UR - https://xlink.rsc.org/?DOI=D2CC03283J

TI - C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes

T2 - Chemical Communications

AU - Narobe, Rok

AU - Murugesan, Kathiravan

AU - Haag, Christoph

AU - Schirmer, Tobias Emanuel

AU - König, Burkhard

PY - 2022

DA - 2022/07/07

PB - Royal Society of Chemistry (RSC)

SP - 8778-8781

IS - 63

VL - 58

PMID - 35843213

SN - 1359-7345

SN - 1364-548X

ER -

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@article{2022_Narobe,

author = {Rok Narobe and Kathiravan Murugesan and Christoph Haag and Tobias Emanuel Schirmer and Burkhard König},

title = {C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes},

journal = {Chemical Communications},

year = {2022},

volume = {58},

publisher = {Royal Society of Chemistry (RSC)},

month = {jul},

url = {https://xlink.rsc.org/?DOI=D2CC03283J},

number = {63},

pages = {8778--8781},

doi = {10.1039/d2cc03283j}

}

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Narobe, Rok, et al. “C(sp3)–H Ritter amination by excitation of in situ generated iodine(iii)–BF3 complexes.” Chemical Communications, vol. 58, no. 63, Jul. 2022, pp. 8778-8781. https://xlink.rsc.org/?DOI=D2CC03283J.