Synthesis, structure and electrochemical properties of 3,4,5-triaryl-1,2-diphosphaferrocenes
Ilya A Bezkishko
1, 2
,
Almaz A Zagidullin
1, 2
,
Mikhail Khrizanforov
1, 2
,
Tatiana I. Gerasimova
1, 2
,
Kamil A Ivshin
1, 2
,
O.N. Kataeva
1, 2
,
Yulia S Ganushevich
3
,
Vasili A Miluykov
1, 2
,
Peter Lönnecke
4
,
Publication type: Journal Article
Publication date: 2022-04-14
scimago Q1
wos Q1
SJR: 1.276
CiteScore: 9.9
Impact factor: 6.4
ISSN: 20521545, 20521553
Inorganic Chemistry
Abstract
Aryl-substituted sodium 1,2-diphosphacyclopentadienides Na(P2C3R3) (R = Ph, 4-Me-C6H4, 4-Cl-C6H4)(1a-c) react with [FeCp(η6-C6H5CH3)][PF6] to give heteroleptic 3,4,5-triaryl-1,2-diphosphaferrocenes [FeCp(η5-P2C3R3)] (2a-c) in 71–78% yield. The structures of 2a-c were confirmed by NMR, UV-Vis spectroscopy and X-ray structure analysis, and supported by DFT calculations. Electrochemical studies of 2a-c in CH3CN demonstrate a pronounced reversible one-electron oxidation, while in the solid state, all 3,4,5-triaryl-1,2-diphosphaferrocenes show fully reversible oxidation and reduction waves, which indicates the stability of the oxidized form. Regardless of the substituent (R = Ph, 4-Me-C6H4, 4-Cl-C6H4), the studied 1,2-diphosphaferrocenes have similar oxidation and reduction potentials.
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Total citations:
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Citations from 2024:
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Bezkishko I. A. et al. Synthesis, structure and electrochemical properties of 3,4,5-triaryl-1,2-diphosphaferrocenes // Inorganic Chemistry Frontiers. 2022. Vol. 9. No. 11. pp. 2608-2616.
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Bezkishko I. A., Zagidullin A. A., Khrizanforov M., Gerasimova T. I., Ivshin K. A., Kataeva O., Ganushevich Y. S., Miluykov V. A., Lönnecke P., Hey-Hawkins E. Synthesis, structure and electrochemical properties of 3,4,5-triaryl-1,2-diphosphaferrocenes // Inorganic Chemistry Frontiers. 2022. Vol. 9. No. 11. pp. 2608-2616.
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TY - JOUR
DO - 10.1039/d2qi00446a
UR - https://xlink.rsc.org/?DOI=D2QI00446A
TI - Synthesis, structure and electrochemical properties of 3,4,5-triaryl-1,2-diphosphaferrocenes
T2 - Inorganic Chemistry Frontiers
AU - Bezkishko, Ilya A
AU - Zagidullin, Almaz A
AU - Khrizanforov, Mikhail
AU - Gerasimova, Tatiana I.
AU - Ivshin, Kamil A
AU - Kataeva, O.N.
AU - Ganushevich, Yulia S
AU - Miluykov, Vasili A
AU - Lönnecke, Peter
AU - Hey-Hawkins, Evamarie
PY - 2022
DA - 2022/04/14
PB - Royal Society of Chemistry (RSC)
SP - 2608-2616
IS - 11
VL - 9
SN - 2052-1545
SN - 2052-1553
ER -
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BibTex (up to 50 authors)
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@article{2022_Bezkishko,
author = {Ilya A Bezkishko and Almaz A Zagidullin and Mikhail Khrizanforov and Tatiana I. Gerasimova and Kamil A Ivshin and O.N. Kataeva and Yulia S Ganushevich and Vasili A Miluykov and Peter Lönnecke and Evamarie Hey-Hawkins},
title = {Synthesis, structure and electrochemical properties of 3,4,5-triaryl-1,2-diphosphaferrocenes},
journal = {Inorganic Chemistry Frontiers},
year = {2022},
volume = {9},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=D2QI00446A},
number = {11},
pages = {2608--2616},
doi = {10.1039/d2qi00446a}
}
Cite this
MLA
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Bezkishko, Ilya A., et al. “Synthesis, structure and electrochemical properties of 3,4,5-triaryl-1,2-diphosphaferrocenes.” Inorganic Chemistry Frontiers, vol. 9, no. 11, Apr. 2022, pp. 2608-2616. https://xlink.rsc.org/?DOI=D2QI00446A.