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Benzocyclobutenone synthesis exploiting acylsilanes as photofunctional directing groups

Тип публикацииJournal Article
Дата публикации2024-10-25
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR2.011
CiteScore12.6
Impact factor7.4
ISSN20416520, 20416539
Краткое описание
The visible-light irradiation of acylsilane tethered vinyl ketones promotes an intramolecular Stetter-type reaction via siloxycarbene intermediates. To exploit this unique mode of reactivity, we herein describe the innovative use of acylsilanes as photofunctional directing groups. First, an acylsilane directed ruthenium catalysed C–H olefination reaction was developed to generate benzoylsilanes bearing vinyl ketone functionality. Then, visible-light irradiation initiated the 1,4-conjugate addition of transient siloxycarbene intermediates with pendent vinyl ketones to afford unique benzocyclobutenone scaffolds primed for further synthetic elaboration.
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ГОСТ |
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Pilkington R. L. et al. Benzocyclobutenone synthesis exploiting acylsilanes as photofunctional directing groups // Chemical Science. 2024. Vol. 15. No. 46. pp. 19328-19335.
ГОСТ со всеми авторами (до 50) Скопировать
Pilkington R. L., Ross H., Atkin L., Priebbenow D. L. Benzocyclobutenone synthesis exploiting acylsilanes as photofunctional directing groups // Chemical Science. 2024. Vol. 15. No. 46. pp. 19328-19335.
RIS |
Цитировать
TY - JOUR
DO - 10.1039/d4sc05715e
UR - https://xlink.rsc.org/?DOI=D4SC05715E
TI - Benzocyclobutenone synthesis exploiting acylsilanes as photofunctional directing groups
T2 - Chemical Science
AU - Pilkington, Rowan L
AU - Ross, Hannah
AU - Atkin, Liselle
AU - Priebbenow, Daniel L
PY - 2024
DA - 2024/10/25
PB - Royal Society of Chemistry (RSC)
SP - 19328-19335
IS - 46
VL - 15
PMID - 39502503
SN - 2041-6520
SN - 2041-6539
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2024_Pilkington,
author = {Rowan L Pilkington and Hannah Ross and Liselle Atkin and Daniel L Priebbenow},
title = {Benzocyclobutenone synthesis exploiting acylsilanes as photofunctional directing groups},
journal = {Chemical Science},
year = {2024},
volume = {15},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=D4SC05715E},
number = {46},
pages = {19328--19335},
doi = {10.1039/d4sc05715e}
}
MLA
Цитировать
Pilkington, Rowan L., et al. “Benzocyclobutenone synthesis exploiting acylsilanes as photofunctional directing groups.” Chemical Science, vol. 15, no. 46, Oct. 2024, pp. 19328-19335. https://xlink.rsc.org/?DOI=D4SC05715E.
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