Physical Chemistry Chemical Physics

, volume 2 , issue 1 , pages 29-35

Effect of matrix and substituent on the electronic structure of trapped benzene radical cations

Vladimir I. Feldman ^{1, 2}

Fedor Sukhov ¹

Aleksei Orlov ²

Ramakant Kadam ³

Yoshiteru Itagaki ³

Anders Lund ³

Hide authors affiliations Show authors affiliations: 3 affiliations

Karpov Institute of Physical Chemistry, Vorontsovo Pole Str. 10, Moscow, Russia |

Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Profsoyuznaya Str. 70, Moscow, Russia |

Department of Physical and Measurement Technology, Linköping University of Technology, Linköping, Sweden |

Publication type: Journal Article

Publication date: 2000-01-01

Royal Society of Chemistry (RSC)

Physical Chemistry Chemical Physics

scimago Q2

wos Q2

SJR: 0.698

CiteScore: 5.3

Impact factor: 2.9

ISSN: 14639076, 14639084

DOI: 10.1039/a906483d

Copy DOI

Physical and Theoretical Chemistry

General Physics and Astronomy

Abstract

The structure and dynamics of the radical cations produced from benzene, monodeuterated benzene and toluene in various low-temperature matrices were characterized by EPR and ENDOR spectroscopy. It was found that the nature of the matrix had a dramatic effect on the EPR spectra of benzene cation. Rigid structures corresponding to the 2B1g and 2B2g states are revealed in solid argon and halocarbon (CFCl3) matrices, respectively, whereas only dynamically averaged patterns are observed in other hosts used (krypton, xenon, sulfur hexafluoride). Deuterium monosubstitution has no appreciable effect on the cation structure observed in argon and halocarbon matrices, which implies matrix control of the preferred electronic state. In contrast, the toluene radical cation exhibits only a 2B2g-like structure both in argon and in CFCl3 matrices, that is, the internal structural effect strongly predominates over environment effects in this case. The results are discussed in qualitative terms taking into consideration the matrix and substituent effects on the charge distribution in benzene cation.

Found

4 citations

Tyurin Daniil

🥼 🤝

PhD in Chemistry

69 publications, 680 citations

h-index: 15

Lomonosov Moscow State University

Computational chemistry

Computational methods in chemistry

Cryogenic technology

EPR spectroscopy

High-performance computing

IR spectroscopy

Interaction of X-ray and synchrotron radiation with matter

Matrix isolation

Molecular modeling

Molecular spectroscopy

Non-covalent Interactions

Non-valent interactions

Top-30

Journals

	1 2 3 4
Journal of Physical Chemistry A	Journal of Physical Chemistry A, 4, 14.81% Journal of Physical Chemistry A 4 publications, 14.81%
Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 3, 11.11% Physical Chemistry Chemical Physics 3 publications, 11.11%
Radiation Physics and Chemistry	Radiation Physics and Chemistry, 2, 7.41% Radiation Physics and Chemistry 2 publications, 7.41%
Low Temperature Physics	Low Temperature Physics, 1, 3.7% Low Temperature Physics 1 publication, 3.7%
Chemical Physics Letters	Chemical Physics Letters, 1, 3.7% Chemical Physics Letters 1 publication, 3.7%
High Energy Chemistry	High Energy Chemistry, 1, 3.7% High Energy Chemistry 1 publication, 3.7%
Journal of the American Chemical Society	Journal of the American Chemical Society, 1, 3.7% Journal of the American Chemical Society 1 publication, 3.7%
Vibronic Interactions and the Jahn-Teller Effect	Vibronic Interactions and the Jahn-Teller Effect, 1, 3.7% Vibronic Interactions and the Jahn-Teller Effect 1 publication, 3.7%
Chemical Reviews	Chemical Reviews, 1, 3.7% Chemical Reviews 1 publication, 3.7%
Journal of Chemical Research	Journal of Chemical Research, 1, 3.7% Journal of Chemical Research 1 publication, 3.7%
Chemical Physics	Chemical Physics, 1, 3.7% Chemical Physics 1 publication, 3.7%
Journal of Physics Condensed Matter	Journal of Physics Condensed Matter, 1, 3.7% Journal of Physics Condensed Matter 1 publication, 3.7%
International Journal of Quantum Chemistry	International Journal of Quantum Chemistry, 1, 3.7% International Journal of Quantum Chemistry 1 publication, 3.7%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 3.7% Angewandte Chemie - International Edition 1 publication, 3.7%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 3.7% Journal of Physical Chemistry C 1 publication, 3.7%
European Journal of Inorganic Chemistry	European Journal of Inorganic Chemistry, 1, 3.7% European Journal of Inorganic Chemistry 1 publication, 3.7%
Angewandte Chemie	Angewandte Chemie, 1, 3.7% Angewandte Chemie 1 publication, 3.7%
Asymmetric Top Molecules. Part 2	Asymmetric Top Molecules. Part 2, 1, 3.7% Asymmetric Top Molecules. Part 2 1 publication, 3.7%
International Journal of Molecular Sciences	International Journal of Molecular Sciences, 1, 3.7% International Journal of Molecular Sciences 1 publication, 3.7%
	1 2 3 4

Publishers

	1 2 3 4 5 6 7
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 25.93% American Chemical Society (ACS) 7 publications, 25.93%
Elsevier	Elsevier, 4, 14.81% Elsevier 4 publications, 14.81%
Springer Nature	Springer Nature, 4, 14.81% Springer Nature 4 publications, 14.81%
Wiley	Wiley, 4, 14.81% Wiley 4 publications, 14.81%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 11.11% Royal Society of Chemistry (RSC) 3 publications, 11.11%
AIP Publishing	AIP Publishing, 1, 3.7% AIP Publishing 1 publication, 3.7%
SAGE	SAGE, 1, 3.7% SAGE 1 publication, 3.7%
IOP Publishing	IOP Publishing, 1, 3.7% IOP Publishing 1 publication, 3.7%
MDPI	MDPI, 1, 3.7% MDPI 1 publication, 3.7%
	1 2 3 4 5 6 7

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Feldman V. I. et al. Effect of matrix and substituent on the electronic structure of trapped benzene radical cations // Physical Chemistry Chemical Physics. 2000. Vol. 2. No. 1. pp. 29-35.

GOST all authors (up to 50) Copy

Feldman V. I., Sukhov F., Orlov A., Kadam R., Itagaki Y., Lund A. Effect of matrix and substituent on the electronic structure of trapped benzene radical cations // Physical Chemistry Chemical Physics. 2000. Vol. 2. No. 1. pp. 29-35.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1039/a906483d

UR - https://xlink.rsc.org/?DOI=a906483d

TI - Effect of matrix and substituent on the electronic structure of trapped benzene radical cations

T2 - Physical Chemistry Chemical Physics

AU - Feldman, Vladimir I.

AU - Sukhov, Fedor

AU - Orlov, Aleksei

AU - Kadam, Ramakant

AU - Itagaki, Yoshiteru

AU - Lund, Anders

PY - 2000

DA - 2000/01/01

PB - Royal Society of Chemistry (RSC)

SP - 29-35

IS - 1

VL - 2

SN - 1463-9076

SN - 1463-9084

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2000_Feldman,

author = {Vladimir I. Feldman and Fedor Sukhov and Aleksei Orlov and Ramakant Kadam and Yoshiteru Itagaki and Anders Lund},

title = {Effect of matrix and substituent on the electronic structure of trapped benzene radical cations},

journal = {Physical Chemistry Chemical Physics},

year = {2000},

volume = {2},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://xlink.rsc.org/?DOI=a906483d},

number = {1},

pages = {29--35},

doi = {10.1039/a906483d}

}

MLA

Cite this

MLA Copy

Feldman, Vladimir I., et al. “Effect of matrix and substituent on the electronic structure of trapped benzene radical cations.” Physical Chemistry Chemical Physics, vol. 2, no. 1, Jan. 2000, pp. 29-35. https://xlink.rsc.org/?DOI=a906483d.