The first isolable pentacoordinate 1,2 lambda 5-azaphosphetine: synthesis, X-ray crystallographic analysis, and dynamic behaviour.
Publication type: Journal Article
Publication date: 2001-10-01
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
DOI:
10.1039/b106501g
PubMed ID:
12240180
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Cycloaddition reaction of an iminophosphorane bearing the Martin ligand with an alkyne gave the first stable 1,2 lambda 5-azaphosphetine, whose structure was determined by X-ray crystallographic analysis, and variable temperature NMR spectroscopy revealed the existence of equilibrium with the corresponding alpha-iminoalkylidenephosphorane.
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Citations from 2025:
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Kano N., Kikuchi A., Kawashima T. The first isolable pentacoordinate 1,2 lambda 5-azaphosphetine: synthesis, X-ray crystallographic analysis, and dynamic behaviour. // Chemical Communications. 2001. Vol. 20. pp. 2096-2097.
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Kano N., Kikuchi A., Kawashima T. The first isolable pentacoordinate 1,2 lambda 5-azaphosphetine: synthesis, X-ray crystallographic analysis, and dynamic behaviour. // Chemical Communications. 2001. Vol. 20. pp. 2096-2097.
Cite this
RIS
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TY - JOUR
DO - 10.1039/b106501g
UR - https://doi.org/10.1039/b106501g
TI - The first isolable pentacoordinate 1,2 lambda 5-azaphosphetine: synthesis, X-ray crystallographic analysis, and dynamic behaviour.
T2 - Chemical Communications
AU - Kano, Naokazu
AU - Kikuchi, Azusa
AU - Kawashima, Takayuki
PY - 2001
DA - 2001/10/01
PB - Royal Society of Chemistry (RSC)
SP - 2096-2097
IS - 20
PMID - 12240180
SN - 1359-7345
SN - 1364-548X
ER -
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@article{2001_Kano,
author = {Naokazu Kano and Azusa Kikuchi and Takayuki Kawashima},
title = {The first isolable pentacoordinate 1,2 lambda 5-azaphosphetine: synthesis, X-ray crystallographic analysis, and dynamic behaviour.},
journal = {Chemical Communications},
year = {2001},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://doi.org/10.1039/b106501g},
number = {20},
pages = {2096--2097},
doi = {10.1039/b106501g}
}