The emission spectrum and the radiative lifetime of Eu3+ in luminescent lanthanide complexes
Publication type: Journal Article
Publication date: 2002-03-22
scimago Q2
wos Q2
SJR: 0.698
CiteScore: 5.3
Impact factor: 2.9
ISSN: 14639076, 14639084
DOI:
10.1039/b107770h
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Although luminescent complexes of lanthanide ions and organic ligands have been studied intensively, relatively little attention has been paid to the natural (or ‘radiative’) lifetime of the lanthanide centered luminescent state in these systems. Here, the applicability of the well-known Judd–Ofelt theory to the emissive properties of Eu3+ complexes is investigated. Moreover, it is demonstrated experimentally that the radiative lifetime of the 5D0 excited state of Eu3+ can be calculated directly from its corrected emission spectrum, without using Judd–Ofelt theory. We also discuss briefly the possibility of finding the natural lifetimes of lanthanide ions other than Eu3+.
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Werts M., Jukes R. T. F., Verhoeven J. W. The emission spectrum and the radiative lifetime of Eu3+ in luminescent lanthanide complexes // Physical Chemistry Chemical Physics. 2002. Vol. 4. No. 9. pp. 1542-1548.
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Werts M., Jukes R. T. F., Verhoeven J. W. The emission spectrum and the radiative lifetime of Eu3+ in luminescent lanthanide complexes // Physical Chemistry Chemical Physics. 2002. Vol. 4. No. 9. pp. 1542-1548.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/b107770h
UR - https://doi.org/10.1039/b107770h
TI - The emission spectrum and the radiative lifetime of Eu3+ in luminescent lanthanide complexes
T2 - Physical Chemistry Chemical Physics
AU - Werts, M.H.V.
AU - Jukes, Ronald T F
AU - Verhoeven, Jan W
PY - 2002
DA - 2002/03/22
PB - Royal Society of Chemistry (RSC)
SP - 1542-1548
IS - 9
VL - 4
SN - 1463-9076
SN - 1463-9084
ER -
Cite this
BibTex (up to 50 authors)
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@article{2002_Werts,
author = {M.H.V. Werts and Ronald T F Jukes and Jan W Verhoeven},
title = {The emission spectrum and the radiative lifetime of Eu3+ in luminescent lanthanide complexes},
journal = {Physical Chemistry Chemical Physics},
year = {2002},
volume = {4},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://doi.org/10.1039/b107770h},
number = {9},
pages = {1542--1548},
doi = {10.1039/b107770h}
}
Cite this
MLA
Copy
Werts, M.H.V., et al. “The emission spectrum and the radiative lifetime of Eu3+ in luminescent lanthanide complexes.” Physical Chemistry Chemical Physics, vol. 4, no. 9, Mar. 2002, pp. 1542-1548. https://doi.org/10.1039/b107770h.