Photochemical and Photobiological Sciences, volume 2, issue 11, pages 1169-1176
Associative return electron transfer. A bond-coupled electron transfer in the photoreactions of cyclopropylamines
Yingsheng Wang
1
,
David K. Luttrull
1
,
Joseph P Dinnocenzo
1
,
Joshua L. Goodman
1
,
Samir Farid
2
,
Ian R Gould
3
1
Department of Chemistry, University of Rochester, Rochester, USA
|
2
Research Laboratories, Eastman Kodak Company, Rochester, USA
|
Publication type: Journal Article
Publication date: 2003-11-18
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.1
ISSN: 1474905X, 14749092
DOI:
10.1039/b306410g
Physical and Theoretical Chemistry
Abstract
The dynamics of the geminate radical-ion pairs formed by electron transfer to the excited states of cyanoanthracenes from 2-phenylcyclopropylamines are dominated by exothermic bond cleavage of the amine radical cations. Quantitative studies of product formation as a function of the energetics of the photochemical and corresponding thermal reactions provide support for a novel mechanism in which return electron transfer in the geminate pair occurs in concert with bond formation from the ring-opened radical cations. This bond-coupled electron transfer process is referred to as an associative return electron transfer reaction. The important features of the associative electron transfer process that explain the experimental observations are described in terms of potential energy surfaces and competition between adiabatic and non-adiabatic deactivation paths.
Top-30
Citations by journals
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1 publication, 7.69%
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1 publication, 7.69%
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ACS Omega
1 publication, 7.69%
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Annual Reports Section B (Organic Chemistry)
1 publication, 7.69%
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1 publication, 7.69%
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Russian Chemical Reviews
1 publication, 7.69%
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1
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Citations by publishers
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1
2
3
4
5
6
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American Chemical Society (ACS)
6 publications, 46.15%
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Elsevier
2 publications, 15.38%
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Society of Synthetic Organic Chemistry
1 publication, 7.69%
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Royal Society of Chemistry (RSC)
1 publication, 7.69%
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Pleiades Publishing
1 publication, 7.69%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.69%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Wang Y. et al. Associative return electron transfer. A bond-coupled electron transfer in the photoreactions of cyclopropylamines // Photochemical and Photobiological Sciences. 2003. Vol. 2. No. 11. pp. 1169-1176.
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Wang Y., Luttrull D. K., Dinnocenzo J. P., Goodman J. L., Farid S., Gould I. R. Associative return electron transfer. A bond-coupled electron transfer in the photoreactions of cyclopropylamines // Photochemical and Photobiological Sciences. 2003. Vol. 2. No. 11. pp. 1169-1176.
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TY - JOUR
DO - 10.1039/b306410g
UR - https://doi.org/10.1039/b306410g
TI - Associative return electron transfer. A bond-coupled electron transfer in the photoreactions of cyclopropylamines
T2 - Photochemical and Photobiological Sciences
AU - Wang, Yingsheng
AU - Luttrull, David K.
AU - Dinnocenzo, Joseph P
AU - Goodman, Joshua L.
AU - Farid, Samir
AU - Gould, Ian R
PY - 2003
DA - 2003/11/18 00:00:00
PB - Springer Nature
SP - 1169-1176
IS - 11
VL - 2
SN - 1474-905X
SN - 1474-9092
ER -
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@article{2003_Wang,
author = {Yingsheng Wang and David K. Luttrull and Joseph P Dinnocenzo and Joshua L. Goodman and Samir Farid and Ian R Gould},
title = {Associative return electron transfer. A bond-coupled electron transfer in the photoreactions of cyclopropylamines},
journal = {Photochemical and Photobiological Sciences},
year = {2003},
volume = {2},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1039/b306410g},
number = {11},
pages = {1169--1176},
doi = {10.1039/b306410g}
}
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Wang, Yingsheng, et al. “Associative return electron transfer. A bond-coupled electron transfer in the photoreactions of cyclopropylamines.” Photochemical and Photobiological Sciences, vol. 2, no. 11, Nov. 2003, pp. 1169-1176. https://doi.org/10.1039/b306410g.