Supramolecular control of [2 + 2] photodimerization via hydrogen bondingThis paper is dedicated to Professor Fred Lewis on the event of his 60th birthday.
Тип публикации: Journal Article
Дата публикации: 2003-11-18
SCImago Q1
WOS Q2
БС1
SJR: 0.636
CiteScore: 6.2
Impact factor: 3.5
ISSN: 1474905X, 14749092
PubMed ID:
14690228
Physical and Theoretical Chemistry
Краткое описание
The use of supramolecular catalysis to control the photoinduced dimerization of styrene, cinnamate, and stilbene chromophores is reported. The strategy employs the formation of a 2 : 1 supramolecular assembly in the presence of 5,5-dihexylbarbituric acid (DHB). A 3- to 10-fold increase in dimerization efficiency is observed in its presence, concomitant with accrued selectivity for the syn photodimers. The origin of the regioselectivity in the presence of DHB is discussed in terms of topochemical control within the supramolecular architecture.
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Darcos V. et al. Supramolecular control of [2 + 2] photodimerization via hydrogen bondingThis paper is dedicated to Professor Fred Lewis on the event of his 60th birthday. // Photochemical and Photobiological Sciences. 2003. Vol. 2. No. 11. p. 1152.
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Darcos V., Griffith K., Sallenave X., Desvergne J., Guyard-Duhayon C., Hasenknopf B., Bassani D. M. Supramolecular control of [2 + 2] photodimerization via hydrogen bondingThis paper is dedicated to Professor Fred Lewis on the event of his 60th birthday. // Photochemical and Photobiological Sciences. 2003. Vol. 2. No. 11. p. 1152.
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TY - JOUR
DO - 10.1039/b307525g
UR - https://doi.org/10.1039/b307525g
TI - Supramolecular control of [2 + 2] photodimerization via hydrogen bondingThis paper is dedicated to Professor Fred Lewis on the event of his 60th birthday.
T2 - Photochemical and Photobiological Sciences
AU - Darcos, Vincent
AU - Griffith, Kirsten
AU - Sallenave, Xavier
AU - Desvergne, Jean-Pierre
AU - Guyard-Duhayon, Carine
AU - Hasenknopf, Bernold
AU - Bassani, Dario M.
PY - 2003
DA - 2003/11/18
PB - Springer Nature
SP - 1152
IS - 11
VL - 2
PMID - 14690228
SN - 1474-905X
SN - 1474-9092
ER -
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@article{2003_Darcos,
author = {Vincent Darcos and Kirsten Griffith and Xavier Sallenave and Jean-Pierre Desvergne and Carine Guyard-Duhayon and Bernold Hasenknopf and Dario M. Bassani},
title = {Supramolecular control of [2 + 2] photodimerization via hydrogen bondingThis paper is dedicated to Professor Fred Lewis on the event of his 60th birthday.},
journal = {Photochemical and Photobiological Sciences},
year = {2003},
volume = {2},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1039/b307525g},
number = {11},
pages = {1152},
doi = {10.1039/b307525g}
}
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MLA
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Darcos, Vincent, et al. “Supramolecular control of [2 + 2] photodimerization via hydrogen bondingThis paper is dedicated to Professor Fred Lewis on the event of his 60th birthday..” Photochemical and Photobiological Sciences, vol. 2, no. 11, Nov. 2003, p. 1152. https://doi.org/10.1039/b307525g.
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