New Journal of Chemistry, volume 29, issue 7, pages 881-894

Novel supramolecular charge-transfer systems based on bis(18-crown-6) stilbene and viologen analogues bearing two ammonioalkylgroups

Vedernikov Artem I. 1
Ushakov E.N. 2
Lobova Natalia A 1
Botsmanova Asya A 1
Strelenko Yuri A. 4
Alfimov Michael V 1
Howard Judith A. 5
Johnels Dan 6
Edlund Ulf G 6
Publication typeJournal Article
Publication date2005-05-11
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3.3
ISSN11440546, 13699261
Materials Chemistry
General Chemistry
Catalysis
Abstract
A series of new viologen analogues bearing two ammonioalkyl groups (2–4) were synthesized in order to study their complexation with bis(18-crown-6)stilbene (1b). Electronic spectroscopy and 1H NMR measurements show that in acetonitrile, bis(crown) stilbene 1b forms highly stable 1 : 1 and 2 : 1 charge-transfer (CT) complexes with π-acceptors 2–4 owing to host–guest bonding. The influence of geometric and electronic factors on the complex formation constants are discussed. The structures of the supramolecular CT complexes are analyzed on the basis of 1H and 13C NMR data obtained in solution and in the solid state. X-Ray diffraction data for 1b and for model tetramethoxystilbene are also reported.

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Fomina M. V. et al. Novel supramolecular charge-transfer systems based on bis(18-crown-6) stilbene and viologen analogues bearing two ammonioalkylgroups // New Journal of Chemistry. 2005. Vol. 29. No. 7. pp. 881-894.
GOST all authors (up to 50) Copy
Fomina M. V., Vedernikov A. I., Ushakov E., Lobova N. A., Botsmanova A. A., Kuz'mina L. G., Churakov A. V., Strelenko Y. A., Alfimov M. V., Howard J. A., Johnels D., Edlund U. G. Novel supramolecular charge-transfer systems based on bis(18-crown-6) stilbene and viologen analogues bearing two ammonioalkylgroups // New Journal of Chemistry. 2005. Vol. 29. No. 7. pp. 881-894.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/b500667h
UR - https://doi.org/10.1039%2Fb500667h
TI - Novel supramolecular charge-transfer systems based on bis(18-crown-6) stilbene and viologen analogues bearing two ammonioalkylgroups
T2 - New Journal of Chemistry
AU - Vedernikov, Artem I.
AU - Lobova, Natalia A
AU - Botsmanova, Asya A
AU - Kuz'mina, Lyudmila G.
AU - Strelenko, Yuri A.
AU - Alfimov, Michael V
AU - Johnels, Dan
AU - Edlund, Ulf G
AU - Fomina, Marina V.
AU - Ushakov, E.N.
AU - Churakov, Andrei V.
AU - Howard, Judith A.
PY - 2005
DA - 2005/05/11 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 881-894
IS - 7
VL - 29
SN - 1144-0546
SN - 1369-9261
ER -
BibTex |
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BibTex Copy
@article{2005_Fomina,
author = {Artem I. Vedernikov and Natalia A Lobova and Asya A Botsmanova and Lyudmila G. Kuz'mina and Yuri A. Strelenko and Michael V Alfimov and Dan Johnels and Ulf G Edlund and Marina V. Fomina and E.N. Ushakov and Andrei V. Churakov and Judith A. Howard},
title = {Novel supramolecular charge-transfer systems based on bis(18-crown-6) stilbene and viologen analogues bearing two ammonioalkylgroups},
journal = {New Journal of Chemistry},
year = {2005},
volume = {29},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://doi.org/10.1039%2Fb500667h},
number = {7},
pages = {881--894},
doi = {10.1039/b500667h}
}
MLA
Cite this
MLA Copy
Fomina, Marina V., et al. “Novel supramolecular charge-transfer systems based on bis(18-crown-6) stilbene and viologen analogues bearing two ammonioalkylgroups.” New Journal of Chemistry, vol. 29, no. 7, May. 2005, pp. 881-894. https://doi.org/10.1039%2Fb500667h.
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