Cp*(iPr3 P)Ru(Cl)(η2-HSiClMe 2 ): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions
Alexander L Osipov
1
,
S. F. Vyboishchikov
2
,
Konstantin Y Dorogov
1
,
Judith A. Howard
4
,
Dmitrii A. Lemenovskii
1
,
G. I. Nikonov
1
Publication type: Journal Article
Publication date: 2005-05-27
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
DOI:
10.1039/b500679a
PubMed ID:
15983670
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to NMR (J(H-Si)= 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane sigma-complex Cp*(iPr3P)Ru(Cl)(eta2-HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand RuCl...SiCl hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group.
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31
Total citations:
31
Citations from 2024:
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Osipov A. L. et al. Cp*(iPr3P)Ru(Cl)(η2-HSiClMe 2): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions // Chemical Communications. 2005. Vol. 26. pp. 3349-3351.
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Osipov A. L., Vyboishchikov S. F., Dorogov K. Y., Kuz'mina L. G., Howard J. A., Lemenovskii D. A., Nikonov G. I. Cp*(iPr3P)Ru(Cl)(η2-HSiClMe 2): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions // Chemical Communications. 2005. Vol. 26. pp. 3349-3351.
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TY - JOUR
DO - 10.1039/b500679a
UR - https://xlink.rsc.org/?DOI=b500679a
TI - Cp*(iPr3P)Ru(Cl)(η2-HSiClMe 2): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions
T2 - Chemical Communications
AU - Osipov, Alexander L
AU - Vyboishchikov, S. F.
AU - Dorogov, Konstantin Y
AU - Kuz'mina, Lyudmila G.
AU - Howard, Judith A.
AU - Lemenovskii, Dmitrii A.
AU - Nikonov, G. I.
PY - 2005
DA - 2005/05/27
PB - Royal Society of Chemistry (RSC)
SP - 3349-3351
IS - 26
PMID - 15983670
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2005_Osipov,
author = {Alexander L Osipov and S. F. Vyboishchikov and Konstantin Y Dorogov and Lyudmila G. Kuz'mina and Judith A. Howard and Dmitrii A. Lemenovskii and G. I. Nikonov},
title = {Cp*(iPr3P)Ru(Cl)(η2-HSiClMe 2): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions},
journal = {Chemical Communications},
year = {2005},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=b500679a},
number = {26},
pages = {3349--3351},
doi = {10.1039/b500679a}
}