Chemical Communications

, издание 26 , страницы 3349-3351

Cp*(ⁱPr3P)Ru(Cl)(η²-HSiClMe 2): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions

Тип публикации: Journal Article

Дата публикации: 2005-05-27

Royal Society of Chemistry (RSC)

Chemical Communications

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SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/b500679a

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PubMed ID: 15983670

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Краткое описание

The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to NMR (J(H-Si)= 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane sigma-complex Cp*(iPr3P)Ru(Cl)(eta2-HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand RuCl...SiCl hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group.

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Чураков Андрей

к.х.н.

557 публикаций, 7 131 цитирование, 14 рецензий

Индекс Хирша: 38

Институт общей и неорганической химии им. Н.С. Курнакова РАН

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Osipov A. L. et al. Cp*(iPr3P)Ru(Cl)(η2-HSiClMe 2): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions // Chemical Communications. 2005. Vol. 26. pp. 3349-3351.

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Osipov A. L., Vyboishchikov S. F., Dorogov K. Y., Kuz'mina L. G., Howard J. A., Lemenovskii D. A., Nikonov G. I. Cp*(iPr3P)Ru(Cl)(η2-HSiClMe 2): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions // Chemical Communications. 2005. Vol. 26. pp. 3349-3351.

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TY - JOUR

DO - 10.1039/b500679a

UR - https://xlink.rsc.org/?DOI=b500679a

TI - Cp*(iPr3P)Ru(Cl)(η2-HSiClMe 2): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions

T2 - Chemical Communications

AU - Osipov, Alexander L

AU - Vyboishchikov, S. F.

AU - Dorogov, Konstantin Y

AU - Kuz'mina, Lyudmila G.

AU - Howard, Judith A.

AU - Lemenovskii, Dmitrii A.

AU - Nikonov, G. I.

PY - 2005

DA - 2005/05/27

PB - Royal Society of Chemistry (RSC)

SP - 3349-3351

IS - 26

PMID - 15983670

SN - 1359-7345

SN - 1364-548X

ER -

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@article{2005_Osipov,

author = {Alexander L Osipov and S. F. Vyboishchikov and Konstantin Y Dorogov and Lyudmila G. Kuz'mina and Judith A. Howard and Dmitrii A. Lemenovskii and G. I. Nikonov},

title = {Cp*(iPr3P)Ru(Cl)(η2-HSiClMe 2): The first complex with simultaneous Si-H and RuCl⋯SiCl inter-ligand inter actions},

journal = {Chemical Communications},

year = {2005},

publisher = {Royal Society of Chemistry (RSC)},

month = {may},

url = {https://xlink.rsc.org/?DOI=b500679a},

number = {26},

pages = {3349--3351},

doi = {10.1039/b500679a}

}