Soft Matter, volume 2, issue 7, pages 608
Tailoring the morphology of emulsion-templated porous polymers
Publication type: Journal Article
Publication date: 2006-05-23
Journal:
Soft Matter
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.4
ISSN: 1744683X, 17446848
DOI:
10.1039/b603211g
General Chemistry
Condensed Matter Physics
Abstract
Methods with which to tailor the morphology of polystyrene-based emulsion-templated (PolyHIPE) materials are presented. Increasing the temperature of the aqueous phase used to prepare the parent emulsion leads to an increase in average void and interconnect size in the resulting porous material. Additionally, the presence in the aqueous phase of small quantities of organic additives that are capable of partitioning between the two emulsion phases also affects the morphology of the porous material obtained. The additives examined were tetrahydrofuran (THF), methanol and poly(ethylene glycol) (PEG), all of which were found to increase the average void and interconnect diameters. It is suggested that THF and, to a lesser extent, PEG enhance Ostwald ripening, resulting in emulsion coarsening over time. Evidence for this was gleaned from NMR experiments to determine the rates of water diffusion in each emulsion. However, methanol was shown not to affect the rate of water diffusion. An alternative mechanism by which methanol could affect the emulsion stability is by depleting surfactant from the interface. However, higher levels of surfactant in emulsions containing methanol did not have a significant effect on morphology. To explain this, we suggest that methanol may result in depletion of surfactant from the emulsion interface, however additional surfactant serves not only to replace this depleted surfactant but also to increase the number of w/o micelles in the continuous phase. These facilitate transport of water between droplets, thus negating the effect of replacing the surfactant lost from the interface.
Citations by journals
|
2
4
6
8
10
12
|
|
|
Polymer
|
Polymer
12 publications, 7.1%
|
|
Journal of Polymer Science, Part A: Polymer Chemistry
|
Journal of Polymer Science, Part A: Polymer Chemistry
10 publications, 5.92%
|
|
Soft Matter
|
Soft Matter
10 publications, 5.92%
|
|
Macromolecules
|
Macromolecules
8 publications, 4.73%
|
|
Biomacromolecules
|
Biomacromolecules
6 publications, 3.55%
|
|
Polymer Chemistry
|
Polymer Chemistry
6 publications, 3.55%
|
|
Colloid and Polymer Science
|
Colloid and Polymer Science
5 publications, 2.96%
|
|
Macromolecular Rapid Communications
|
Macromolecular Rapid Communications
5 publications, 2.96%
|
|
Journal of Materials Chemistry
|
Journal of Materials Chemistry
5 publications, 2.96%
|
|
Reactive and Functional Polymers
|
Reactive and Functional Polymers
4 publications, 2.37%
|
|
Langmuir
|
Langmuir
4 publications, 2.37%
|
|
European Polymer Journal
|
European Polymer Journal
3 publications, 1.78%
|
|
Journal of Applied Polymer Science
|
Journal of Applied Polymer Science
3 publications, 1.78%
|
|
Macromolecular Chemistry and Physics
|
Macromolecular Chemistry and Physics
3 publications, 1.78%
|
|
Advanced Materials
|
Advanced Materials
3 publications, 1.78%
|
|
ACS applied materials & interfaces
|
ACS applied materials & interfaces
3 publications, 1.78%
|
|
Tissue Engineering - Part A.
|
Tissue Engineering - Part A.
2 publications, 1.18%
|
|
Polymers
|
Polymers
2 publications, 1.18%
|
|
European Physical Journal E
|
European Physical Journal E
2 publications, 1.18%
|
|
Scientific Reports
|
Scientific Reports
2 publications, 1.18%
|
|
Journal of Porous Materials
|
Journal of Porous Materials
2 publications, 1.18%
|
|
Advanced Engineering Materials
|
Advanced Engineering Materials
2 publications, 1.18%
|
|
Macromolecular Bioscience
|
Macromolecular Bioscience
2 publications, 1.18%
|
|
Journal of Anatomy
|
Journal of Anatomy
2 publications, 1.18%
|
|
Advanced Functional Materials
|
Advanced Functional Materials
2 publications, 1.18%
|
|
Chemical Communications
|
Chemical Communications
2 publications, 1.18%
|
|
Journal of Materials Chemistry A
|
Journal of Materials Chemistry A
2 publications, 1.18%
|
|
RSC Advances
|
RSC Advances
2 publications, 1.18%
|
|
Cellular and Molecular Life Sciences
|
Cellular and Molecular Life Sciences
1 publication, 0.59%
|
|
2
4
6
8
10
12
|
Citations by publishers
|
5
10
15
20
25
30
35
40
45
|
|
|
Wiley
|
Wiley
43 publications, 25.44%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
33 publications, 19.53%
|
|
Elsevier
|
Elsevier
27 publications, 15.98%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
27 publications, 15.98%
|
|
Springer Nature
|
Springer Nature
18 publications, 10.65%
|
|
Mary Ann Liebert
|
Mary Ann Liebert
4 publications, 2.37%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
4 publications, 2.37%
|
|
Taylor & Francis
|
Taylor & Francis
2 publications, 1.18%
|
|
Portland Press
|
Portland Press
1 publication, 0.59%
|
|
SAGE
|
SAGE
1 publication, 0.59%
|
|
Frontiers Media S.A.
|
Frontiers Media S.A.
1 publication, 0.59%
|
|
KeAi Communications Co.
|
KeAi Communications Co.
1 publication, 0.59%
|
|
Hindawi Limited
|
Hindawi Limited
1 publication, 0.59%
|
|
5
10
15
20
25
30
35
40
45
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2007,2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[11,7,11,9,12,11,16,12,5,7,9,10,14,9,10,5,9,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["6.51","4.14","6.51","5.33","7.1","6.51","9.47","7.1","2.96","4.14","5.33","5.92","8.28","5.33","5.92","2.96","5.33","1.18"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Polymer","Journal of Polymer Science, Part A: Polymer Chemistry","Soft Matter","Macromolecules","Biomacromolecules","Polymer Chemistry","Colloid and Polymer Science","Macromolecular Rapid Communications","Journal of Materials Chemistry","Reactive and Functional Polymers","Langmuir","European Polymer Journal","Journal of Applied Polymer Science","Macromolecular Chemistry and Physics","Advanced Materials","ACS applied materials & interfaces","Tissue Engineering - Part A.","Polymers","European Physical Journal E","Scientific Reports","Journal of Porous Materials","Advanced Engineering Materials","Macromolecular Bioscience","Journal of Anatomy","Advanced Functional Materials","Chemical Communications","Journal of Materials Chemistry A","RSC Advances","Cellular and Molecular Life Sciences"],"ids":[19955,10573,15507,20817,23815,11501,20223,13443,25319,5047,19601,17319,513,17090,25159,1458,3218,11204,10807,13767,18030,18649,7939,4068,7715,9073,14919,3100,5151],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/Zy5YST233rzRbZP24I24MzZm64hz20ZV9qQopmMn_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp"],"datasets":[{"label":"","data":[12,10,10,8,6,6,5,5,5,4,4,3,3,3,3,3,2,2,2,2,2,2,2,2,2,2,2,2,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[7.1,5.92,5.92,4.73,3.55,3.55,2.96,2.96,2.96,2.37,2.37,1.78,1.78,1.78,1.78,1.78,1.18,1.18,1.18,1.18,1.18,1.18,1.18,1.18,1.18,1.18,1.18,1.18,0.59],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","Royal Society of Chemistry (RSC)","Elsevier","American Chemical Society (ACS)","Springer Nature","Mary Ann Liebert","Multidisciplinary Digital Publishing Institute (MDPI)","Taylor & Francis","Portland Press","SAGE","Frontiers Media S.A.","KeAi Communications Co.","Hindawi Limited"],"ids":[11,123,17,40,8,230,202,18,801,31,208,326,6921],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/Zy5YST233rzRbZP24I24MzZm64hz20ZV9qQopmMn_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/nUqNrP9GnM1t0BrAIXp1LBodjU8aIJ2Fk4pLfGhZ_medium.webp","\/storage\/images\/resized\/ruydfaB80LDjlkYqsfOeUAZohOIODyq7bQzis5O7_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/jeWDR7NTA9Ab5MVz8Uqjl2RPCndzFjSyl0FaRAHg_medium.webp","\/storage\/images\/resized\/hqfzhQAjTGlNSRs6yzFNITgjSMm9Jr2QuotJHIvE_medium.webp"],"datasets":[{"label":"","data":[43,33,27,27,18,4,4,2,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[25.44,19.53,15.98,15.98,10.65,2.37,2.37,1.18,0.59,0.59,0.59,0.59,0.59],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Carnachan R. J. et al. Tailoring the morphology of emulsion-templated porous polymers // Soft Matter. 2006. Vol. 2. No. 7. p. 608.
GOST all authors (up to 50)
Copy
Carnachan R. J., Maria B., Przyborski S. A., Cameron N. Tailoring the morphology of emulsion-templated porous polymers // Soft Matter. 2006. Vol. 2. No. 7. p. 608.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/b603211g
UR - https://doi.org/10.1039%2Fb603211g
TI - Tailoring the morphology of emulsion-templated porous polymers
T2 - Soft Matter
AU - Carnachan, Ross J
AU - Maria, Bokhari
AU - Przyborski, S. A.
AU - Cameron, Neil
PY - 2006
DA - 2006/05/23 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 608
IS - 7
VL - 2
SN - 1744-683X
SN - 1744-6848
ER -
Cite this
BibTex
Copy
@article{2006_Carnachan,
author = {Ross J Carnachan and Bokhari Maria and S. A. Przyborski and Neil Cameron},
title = {Tailoring the morphology of emulsion-templated porous polymers},
journal = {Soft Matter},
year = {2006},
volume = {2},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://doi.org/10.1039%2Fb603211g},
number = {7},
pages = {608},
doi = {10.1039/b603211g}
}
Cite this
MLA
Copy
Carnachan, Ross J., et al. “Tailoring the morphology of emulsion-templated porous polymers.” Soft Matter, vol. 2, no. 7, May. 2006, p. 608. https://doi.org/10.1039%2Fb603211g.