Journal of Materials Chemistry A

, том 17 , издание 7 , страницы 692-698

Synthesis and crystal structure of the Sr2Al1.07Mn0.93O5 brownmillerite

Тип публикации: Journal Article

Дата публикации: 2007-01-01

Royal Society of Chemistry (RSC)

Journal of Materials Chemistry A

scimago Q1

wos Q1

БС1

SJR: 2.462

CiteScore: 16.7

Impact factor: 9.5

ISSN: 20507488, 20507496, 09599428, 13645501

DOI: 10.1039/b614168d

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Materials Chemistry

General Chemistry

Краткое описание

A new brownmillerite-type compound Sr2Al1.07Mn0.93O5 was synthesized. The crystal structure was determined using electron diffraction and high resolution transmission electron microscopy and refined from X-ray powder diffraction data (space group Imma, a = 5.4358(1) A, b = 15.6230(4) A, c = 5.6075(1) A, RI = 0.036, RP = 0.023). The structure is characterized by a disordered distribution of the tetrahedral chains in L and R configuration and a partial occupation of the octahedral position by the Mn3+ and Al3+ cations. The relationships between the crystal structures of Sr2Al1.07Mn0.93O5 and its A2B′MnO5 analogues (A = Ca, Sr, B′ = Al, Ga) and the structural reasons for the different types of tetrahedral chain ordering in brownmillerites are discussed. The temperature dependences of the magnetic susceptibility and specific heat reveal that the compound is antiferromagnetically ordered below TN = 105 K.

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5 цитирований

Антипов Евгений

д.х.н., проф., академик, Российская академия наук

466 публикаций, 10 708 цитирований, 29 рецензий

Индекс Хирша: 50

Московский государственный университет имени М.В. Ломоносова

Сколковский институт науки и технологий

1 цитирование

Истомин Сергей

к.х.н.

101 публикация, 2 120 цитирований, 12 рецензий

Индекс Хирша: 25

Московский государственный университет имени М.В. Ломоносова

1 цитирование

Бедарькова Анжелика

к.х.н.

52 публикации, 489 цитирований, 1 рецензия

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Институт высокотемпературной электрохимии УрО РАН

Уральский федеральный университет имени первого Президента России Б.Н. Ельцина

Институт общей и неорганической химии им. Н.С. Курнакова РАН

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Hadermann J. et al. Synthesis and crystal structure of the Sr2Al1.07Mn0.93O5 brownmillerite // Journal of Materials Chemistry A. 2007. Vol. 17. No. 7. pp. 692-698.

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Hadermann J., Abakumov A. M., D'Hondt H., Kalyuzhnaya A. S., Rozova M. G., Markina M. M., Mikheev M. G., Tristan N., Клингелер Р., Büchner B., Antipov E. V. Synthesis and crystal structure of the Sr2Al1.07Mn0.93O5 brownmillerite // Journal of Materials Chemistry A. 2007. Vol. 17. No. 7. pp. 692-698.

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TY - JOUR

DO - 10.1039/b614168d

UR - https://xlink.rsc.org/?DOI=B614168D

TI - Synthesis and crystal structure of the Sr2Al1.07Mn0.93O5 brownmillerite

T2 - Journal of Materials Chemistry A

AU - Hadermann, Joke

AU - Abakumov, Artem M.

AU - D'Hondt, Hans

AU - Kalyuzhnaya, Anna S

AU - Rozova, Marina G

AU - Markina, Maria M.

AU - Mikheev, Mikhail G

AU - Tristan, Natalia

AU - Клингелер, Р.

AU - Büchner, B.

AU - Antipov, Evgeny V.

PY - 2007

DA - 2007/01/01

PB - Royal Society of Chemistry (RSC)

SP - 692-698

IS - 7

VL - 17

SN - 2050-7488

SN - 2050-7496

SN - 0959-9428

SN - 1364-5501

ER -

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@article{2007_Hadermann,

author = {Joke Hadermann and Artem M. Abakumov and Hans D'Hondt and Anna S Kalyuzhnaya and Marina G Rozova and Maria M. Markina and Mikhail G Mikheev and Natalia Tristan and Р. Клингелер and B. Büchner and Evgeny V. Antipov},

title = {Synthesis and crystal structure of the Sr2Al1.07Mn0.93O5 brownmillerite},

journal = {Journal of Materials Chemistry A},

year = {2007},

volume = {17},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://xlink.rsc.org/?DOI=B614168D},

number = {7},

pages = {692--698},

doi = {10.1039/b614168d}

}

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Hadermann, Joke, et al. “Synthesis and crystal structure of the Sr2Al1.07Mn0.93O5 brownmillerite.” Journal of Materials Chemistry A, vol. 17, no. 7, Jan. 2007, pp. 692-698. https://xlink.rsc.org/?DOI=B614168D.