Titanium complexes based on chiral enantiopure dialkanolamines: Synthesis, structures and catalytic activity
K V Zaitsev
1
,
M.V. Bermeshev
1
,
Alexey A Samsonov
1
,
Juri F Oprunenko
1
,
Judith A L Howard
3
,
Sergey S. Karlov
1
,
Galina S. Zaitseva
1
Publication type: Journal Article
Publication date: 2008-04-15
scimago Q2
wos Q3
SJR: 0.493
CiteScore: 5.0
Impact factor: 2.5
ISSN: 11440546, 13699261
DOI:
10.1039/b714739b
Materials Chemistry
General Chemistry
Catalysis
Abstract
New chiral enantiopure tridentate ligands (dialkanolamines) RN(CHR3CR1R2OH)(CHR4CR5R6OH) 10–17 were synthesized by the opening of the epoxide ring by the action of the amines or alkanolamines. Titanium complexes, viz. [RN(CHR3CR1R2O)(CHR4CR5R6O)]Ti(O-i-Pr)218–23 and [RN(CHR3CR1R2O)(CHR4CR5R6O)]2Ti 25–31 were synthesized by treatment of Ti(O-i-Pr)4 with one or two equivalents of corresponding dialkanolamines. Complex (R)-PhCH(Me)N(CH2C(Me)2O)2TiCl2*HNMe224 was obtained from the reaction of one equivalent of dialkanolamine 10 with (Me2N)2TiCl2. The composition and structure of all novel compounds were established by 1H and 13C NMR spectroscopy as well as elemental analysis. The possible solution structures of 18–31 are discussed. The single-crystal X-ray diffraction study of 23, 25–28, 30, 31 indicates monomeric structures in the solid state. Chiral complexes 20, 22, 23, 25, 26, 30 were tested as chiral catalysts in the Abramov reaction and demonstrated moderate enantiomeric activity.
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Total citations:
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Citations from 2024:
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GOST
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Zaitsev K. V. et al. Titanium complexes based on chiral enantiopure dialkanolamines: Synthesis, structures and catalytic activity // New Journal of Chemistry. 2008. Vol. 32. No. 8. pp. 1415-1431.
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Zaitsev K. V., Zaitsev K. V., Bermeshev M., Samsonov A. A., Oprunenko J. F., Churakov A. V., Howard J. A. L., Karlov S. S., Zaitseva G. S. Titanium complexes based on chiral enantiopure dialkanolamines: Synthesis, structures and catalytic activity // New Journal of Chemistry. 2008. Vol. 32. No. 8. pp. 1415-1431.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/b714739b
UR - https://xlink.rsc.org/?DOI=b714739b
TI - Titanium complexes based on chiral enantiopure dialkanolamines: Synthesis, structures and catalytic activity
T2 - New Journal of Chemistry
AU - Zaitsev, K V
AU - Zaitsev, Kirill V.
AU - Bermeshev, M.V.
AU - Samsonov, Alexey A
AU - Oprunenko, Juri F
AU - Churakov, Andrei V.
AU - Howard, Judith A L
AU - Karlov, Sergey S.
AU - Zaitseva, Galina S.
PY - 2008
DA - 2008/04/15
PB - Royal Society of Chemistry (RSC)
SP - 1415-1431
IS - 8
VL - 32
SN - 1144-0546
SN - 1369-9261
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_Zaitsev,
author = {K V Zaitsev and Kirill V. Zaitsev and M.V. Bermeshev and Alexey A Samsonov and Juri F Oprunenko and Andrei V. Churakov and Judith A L Howard and Sergey S. Karlov and Galina S. Zaitseva},
title = {Titanium complexes based on chiral enantiopure dialkanolamines: Synthesis, structures and catalytic activity},
journal = {New Journal of Chemistry},
year = {2008},
volume = {32},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=b714739b},
number = {8},
pages = {1415--1431},
doi = {10.1039/b714739b}
}
Cite this
MLA
Copy
Zaitsev, K. V., et al. “Titanium complexes based on chiral enantiopure dialkanolamines: Synthesis, structures and catalytic activity.” New Journal of Chemistry, vol. 32, no. 8, Apr. 2008, pp. 1415-1431. https://xlink.rsc.org/?DOI=b714739b.