Cationic rare-earth metal bis(tetrahydridoborato) complexes: direct synthesis, structure and ring-opening polymerisation activity toward cyclic esters
Publication type: Journal Article
Publication date: 2008-05-07
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
DOI:
10.1039/b801030g
PubMed ID:
18688395
Inorganic Chemistry
Abstract
Rare-earth metal tris(borohydrides) [Ln(BH4)3(thf)3] (Ln = Y, La, Nd, Sm) are converted with one equivalent of the Brønsted acid [NEt3H]+[BPh4]- in thf into the monocationic bis(borohydride) complexes [Ln(BH4)2(thf)5]+[BPh4]-. They efficiently initiate the ring-opening polymerisation of epsilon-caprolactone.
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43
Total citations:
43
Citations from 2025:
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Robert D., Kondracka M., Okuda J. Cationic rare-earth metal bis(tetrahydridoborato) complexes: direct synthesis, structure and ring-opening polymerisation activity toward cyclic esters // Dalton Transactions. 2008. Vol. 20. p. 2667.
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Robert D., Kondracka M., Okuda J. Cationic rare-earth metal bis(tetrahydridoborato) complexes: direct synthesis, structure and ring-opening polymerisation activity toward cyclic esters // Dalton Transactions. 2008. Vol. 20. p. 2667.
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TY - JOUR
DO - 10.1039/b801030g
UR - https://doi.org/10.1039/b801030g
TI - Cationic rare-earth metal bis(tetrahydridoborato) complexes: direct synthesis, structure and ring-opening polymerisation activity toward cyclic esters
T2 - Dalton Transactions
AU - Robert, Dominique
AU - Kondracka, Małgorzata
AU - Okuda, Jun
PY - 2008
DA - 2008/05/07
PB - Royal Society of Chemistry (RSC)
SP - 2667
IS - 20
PMID - 18688395
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_Robert,
author = {Dominique Robert and Małgorzata Kondracka and Jun Okuda},
title = {Cationic rare-earth metal bis(tetrahydridoborato) complexes: direct synthesis, structure and ring-opening polymerisation activity toward cyclic esters},
journal = {Dalton Transactions},
year = {2008},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://doi.org/10.1039/b801030g},
number = {20},
pages = {2667},
doi = {10.1039/b801030g}
}
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