1,1- and 1,2-isomers of the diborane(4) compound B2{1,2-(NH)2C6H4}2 and a TCNQ Co-crystal of the 1,1-isomer
Тип публикации: Journal Article
Дата публикации: 2009-05-20
SCImago Q2
WOS Q2
БС1
SJR: 0.581
CiteScore: 6
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
19565086
Inorganic Chemistry
Краткое описание
The synthesis and X-ray crystal structures of the diborane(4) isomers 1,1-B(2){1,2-(NH)(2)C(6)H(4)}(2) and 1,2-B(2){1,2-(NH)(2)C(6)H(4)}(2) are described together with the results of quantum chemical calculations which shed light on their relative stabilities and degree of aromaticity. Spectroscopic data are also provided for both isomers of the 4-methyl aryl derivative. The compound 1,1-B(2){1-O-2-(NH)C(6)H(4)}(2) has also been prepared and structurally characterised but no evidence was obtained for the corresponding 1,2-isomer. The compound 1,1-B(2){1,2-(NH)(2)C(6)H(4)}(2) forms a co-crystal with TCNQ, the structure of which is also reported.
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Alibadi M. A. M. et al. 1,1- and 1,2-isomers of the diborane(4) compound B2{1,2-(NH)2C6H4}2 and a TCNQ Co-crystal of the 1,1-isomer // Dalton Transactions. 2009. Vol. 27. p. 5348.
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Alibadi M. A. M., Batsanov A. S., Bramham G., Charmant J. P. H., Haddow M. F., Mackay L., Mansell S. M., McGrady J. E., Norman N. C., Roffey A., Russell C. T. 1,1- and 1,2-isomers of the diborane(4) compound B2{1,2-(NH)2C6H4}2 and a TCNQ Co-crystal of the 1,1-isomer // Dalton Transactions. 2009. Vol. 27. p. 5348.
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TY - JOUR
DO - 10.1039/b822225h
UR - https://doi.org/10.1039/b822225h
TI - 1,1- and 1,2-isomers of the diborane(4) compound B2{1,2-(NH)2C6H4}2 and a TCNQ Co-crystal of the 1,1-isomer
T2 - Dalton Transactions
AU - Alibadi, M A M
AU - Batsanov, Andrei S.
AU - Bramham, G
AU - Charmant, J. P. H.
AU - Haddow, Mairi F.
AU - Mackay, L.
AU - Mansell, S M
AU - McGrady, John E.
AU - Norman, N. C.
AU - Roffey, Anna
AU - Russell, C. T.
PY - 2009
DA - 2009/05/20
PB - Royal Society of Chemistry (RSC)
SP - 5348
IS - 27
PMID - 19565086
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2009_Alibadi,
author = {M A M Alibadi and Andrei S. Batsanov and G Bramham and J. P. H. Charmant and Mairi F. Haddow and L. Mackay and S M Mansell and John E. McGrady and N. C. Norman and Anna Roffey and C. T. Russell},
title = {1,1- and 1,2-isomers of the diborane(4) compound B2{1,2-(NH)2C6H4}2 and a TCNQ Co-crystal of the 1,1-isomer},
journal = {Dalton Transactions},
year = {2009},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://doi.org/10.1039/b822225h},
number = {27},
pages = {5348},
doi = {10.1039/b822225h}
}
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