Molecular tailoring of spin-transition materials: preparation, crystal structure and magnetism of trifluoromethyl-pyridyl-1,3,2-dithiazolyl
Publication type: Journal Article
Publication date: 2011-01-31
scimago Q2
wos Q2
SJR: 0.520
CiteScore: 5.2
Impact factor: 2.6
ISSN: 14668033
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The α-phase of pyridyl-1,3,2-dithiazolyl, pyDTA, has previously been shown to exhibit a distorted π-stacked structure which is diamagnetic at low temperature. Unlike other π-stacked dithiazolyl radicals it does not undergo a first order phase transition to a regular π-stacked paramagnetic phase even upon warming to its melting point. Here we show that incorporation of a trifluoromethyl group destabilises the diamagnetic π*–π* dimer and the title compound (1) exhibits a spin-transition (without hysteresis) at 50 K.
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32
Total citations:
32
Citations from 2025:
1
(3.13%)
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GOST
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Olaso-Gonzalez G. et al. Molecular tailoring of spin-transition materials: preparation, crystal structure and magnetism of trifluoromethyl-pyridyl-1,3,2-dithiazolyl // CrystEngComm. 2011. Vol. 13. No. 6. p. 1794.
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Olaso-Gonzalez G., Eisler D. J., Harvey L., Rawson J. M. Molecular tailoring of spin-transition materials: preparation, crystal structure and magnetism of trifluoromethyl-pyridyl-1,3,2-dithiazolyl // CrystEngComm. 2011. Vol. 13. No. 6. p. 1794.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c0ce00893a
UR - https://doi.org/10.1039/c0ce00893a
TI - Molecular tailoring of spin-transition materials: preparation, crystal structure and magnetism of trifluoromethyl-pyridyl-1,3,2-dithiazolyl
T2 - CrystEngComm
AU - Olaso-Gonzalez, Gloria
AU - Eisler, Dana J.
AU - Harvey, Laura
AU - Rawson, Jeremy M.
PY - 2011
DA - 2011/01/31
PB - Royal Society of Chemistry (RSC)
SP - 1794
IS - 6
VL - 13
SN - 1466-8033
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Olaso-Gonzalez,
author = {Gloria Olaso-Gonzalez and Dana J. Eisler and Laura Harvey and Jeremy M. Rawson},
title = {Molecular tailoring of spin-transition materials: preparation, crystal structure and magnetism of trifluoromethyl-pyridyl-1,3,2-dithiazolyl},
journal = {CrystEngComm},
year = {2011},
volume = {13},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c0ce00893a},
number = {6},
pages = {1794},
doi = {10.1039/c0ce00893a}
}
Cite this
MLA
Copy
Olaso-Gonzalez, Gloria, et al. “Molecular tailoring of spin-transition materials: preparation, crystal structure and magnetism of trifluoromethyl-pyridyl-1,3,2-dithiazolyl.” CrystEngComm, vol. 13, no. 6, Jan. 2011, p. 1794. https://doi.org/10.1039/c0ce00893a.