Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS′-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides
V. A. Kozlov
1
,
L.N. Puntus
2
,
E I Gutsul
1
,
N E Shepel
1
,
A. A. Vasilev
3
,
P.V Petrovskii
1
,
I. L. Odinets
1
Publication type: Journal Article
Publication date: 2011-01-04
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
21203625
Inorganic Chemistry
Abstract
Novel unsymmetrical SCS'-pincer ligands, 1-[PhNHC(S)]-3-[Ph(2)P(S)NH]-C(6)H(4) (3) and 1-[PhNHC(S)]-3-[Ph(2)P(S)O]C(6)H(4) (7), bearing a thiocarbamoyl moiety in combination with thiophosphorylamino- and thiophosphoryloxy-donating groups, respectively, were obtained via thiophosphorylation of 3-amino- and 3-hydroxy-benzoic acid (thio)anilides 1 and 6. Direct cyclometallation of the central benzene ring in the ligands 3 and 7 in reaction with (PhCN)(2)MCl(2) (M = Pd, Pt) as a metal precursor afforded κ(3)-SCS'-hybrid pincer complexes 8, 9 with 5- and 6-membered fused metallacycles in good to high yields (67-95%). The complexes 8 and 9 were characterized by multinuclear NMR ((31)P, (1)H, (13)C) and IR spectroscopy as well as single-crystal X-ray crystallography. Palladium complexes 8a and 9a were shown to be active catalysts for the Suzuki-Miyaura cross-coupling reaction. In the solid state the ligands 3 and 7 as well as their Pt(II) and Pd(II) complexes 8 and 9 are luminescent at 300 K. The emission of the complexes has the different origin depending on the metal nature.
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V. Aleksanyan D. et al. Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS′-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides // Dalton Transactions. 2011. Vol. 40. No. 7. p. 1535.
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V. Aleksanyan D., Kozlov V. A., Nelyubina Y. V., Lyssenko K. A., Puntus L., Gutsul E. I., Shepel N. E., Vasilev A. A., Petrovskii P., Odinets I. L. Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS′-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides // Dalton Transactions. 2011. Vol. 40. No. 7. p. 1535.
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TY - JOUR
DO - 10.1039/c0dt01154a
UR - https://xlink.rsc.org/?DOI=c0dt01154a
TI - Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS′-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides
T2 - Dalton Transactions
AU - V. Aleksanyan, Diana
AU - Kozlov, V. A.
AU - Nelyubina, Yulia V.
AU - Lyssenko, Konstantin A.
AU - Puntus, L.N.
AU - Gutsul, E I
AU - Shepel, N E
AU - Vasilev, A. A.
AU - Petrovskii, P.V
AU - Odinets, I. L.
PY - 2011
DA - 2011/01/04
PB - Royal Society of Chemistry (RSC)
SP - 1535
IS - 7
VL - 40
PMID - 21203625
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_V. Aleksanyan,
author = {Diana V. Aleksanyan and V. A. Kozlov and Yulia V. Nelyubina and Konstantin A. Lyssenko and L.N. Puntus and E I Gutsul and N E Shepel and A. A. Vasilev and P.V Petrovskii and I. L. Odinets},
title = {Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS′-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides},
journal = {Dalton Transactions},
year = {2011},
volume = {40},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=c0dt01154a},
number = {7},
pages = {1535},
doi = {10.1039/c0dt01154a}
}
Cite this
MLA
Copy
V. Aleksanyan, Diana, et al. “Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS′-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides.” Dalton Transactions, vol. 40, no. 7, Jan. 2011, p. 1535. https://xlink.rsc.org/?DOI=c0dt01154a.