Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation
Aurélien Momin
1
,
F. Bonnet
2
,
M. Visseaux
2
,
Laurent Maron
3
,
Josef Takats
4
,
M. J. Ferguson
4
,
Xavier Frédéric Le Goff
1
,
Xavier-Frédéric Le Goff
1
,
François Nief
1
1
Ecole Polytechnique, CNRS, Laboratoire Hétéroéléments et Coordination, Palaiseau, France
|
Publication type: Journal Article
Publication date: 2011-10-11
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
21987051
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The new divalent thulium compound [Tm(BH(4))(2)(DME)(2)] could be prepared by reduction of [Tm(BH(4))(3)(THF)(3)] or from TmI(2) and KBH(4). It was used as a precursor to the divalent [(Tp(tBu,Me))Tm(BH(4))(THF)] by reaction with potassium tris(2-tBu-4-Me)pyrazolylborate (KTp(tBu,Me)). Both Tm(II) compounds were found active as ε-caprolactone polymerisation catalysts.
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Total citations:
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Momin A. et al. Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation // Chemical Communications. 2011. Vol. 47. No. 44. p. 12203.
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Momin A., Bonnet F., Visseaux M., Maron L., Takats J., Ferguson M. J., Le Goff X. F., Le Goff X., Nief F. Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation // Chemical Communications. 2011. Vol. 47. No. 44. p. 12203.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c1cc15294g
UR - https://doi.org/10.1039/c1cc15294g
TI - Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation
T2 - Chemical Communications
AU - Momin, Aurélien
AU - Bonnet, F.
AU - Visseaux, M.
AU - Maron, Laurent
AU - Takats, Josef
AU - Ferguson, M. J.
AU - Le Goff, Xavier Frédéric
AU - Le Goff, Xavier-Frédéric
AU - Nief, François
PY - 2011
DA - 2011/10/11
PB - Royal Society of Chemistry (RSC)
SP - 12203
IS - 44
VL - 47
PMID - 21987051
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Momin,
author = {Aurélien Momin and F. Bonnet and M. Visseaux and Laurent Maron and Josef Takats and M. J. Ferguson and Xavier Frédéric Le Goff and Xavier-Frédéric Le Goff and François Nief},
title = {Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation},
journal = {Chemical Communications},
year = {2011},
volume = {47},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://doi.org/10.1039/c1cc15294g},
number = {44},
pages = {12203},
doi = {10.1039/c1cc15294g}
}
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MLA
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Momin, Aurélien, et al. “Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation.” Chemical Communications, vol. 47, no. 44, Oct. 2011, p. 12203. https://doi.org/10.1039/c1cc15294g.
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