Selective one-step synthesis of triple-decker (porphyrinato) (phthalocyaninato) early lanthanides: The balance of concurrent processes
Publication type: Journal Article
Publication date: 2011-09-27
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
21952519
Inorganic Chemistry
Abstract
An effective one-step approach for the preparation of (porphyrinato)(phthalocyaninato) early lanthanides of type [Br(4)TPP]Ln[(15C5)(4)Pc]Ln[Br(4)TPP], where Br(4)TPP = 5,10,15,20-tetrakis-(4-bromophenyl)-porphyrinato-ligand, (15C5)(4)Pc = tetrakis-(15-crown-5)-phthalocyaninato-ligand and Ln = La, Pr, Nd or Eu, is developed. The influence of various factors on the reaction pathway and yields of the complexes is investigated in detail. The developed protocol is found to be general for the early lanthanide subgroup. Variation of the synthetic conditions allowed the determination and isolation of possible side-products, namely heteroleptic double-deckers [Br(4)TPP]Ln[(15C5)(4)Pc] (Ln = Nd, Eu) and triple-decker [Br(4)TPP]Nd[(15C5)(4)Pc]Nd[(15C5)(4)Pc]. The peculiarities of the NMR lanthanide-induced shifts (LIS) of resonances of the synthesized triple-decker complexes are precisely investigated. The isostructurality of the synthesized complexes within the series as well as isostructurality with previously synthesized compounds is demonstrated in terms of two-nuclei analysis of LIS.
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Birin K. P. et al. Selective one-step synthesis of triple-decker (porphyrinato) (phthalocyaninato) early lanthanides: The balance of concurrent processes // Dalton Transactions. 2011. Vol. 40. No. 43. pp. 11539-11549.
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Birin K. P., Gorbunova Y. G., Tsivadze A. Selective one-step synthesis of triple-decker (porphyrinato) (phthalocyaninato) early lanthanides: The balance of concurrent processes // Dalton Transactions. 2011. Vol. 40. No. 43. pp. 11539-11549.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c1dt11141h
UR - https://xlink.rsc.org/?DOI=c1dt11141h
TI - Selective one-step synthesis of triple-decker (porphyrinato) (phthalocyaninato) early lanthanides: The balance of concurrent processes
T2 - Dalton Transactions
AU - Birin, Kirill P.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan
PY - 2011
DA - 2011/09/27
PB - Royal Society of Chemistry (RSC)
SP - 11539-11549
IS - 43
VL - 40
PMID - 21952519
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Birin,
author = {Kirill P. Birin and Yulia G. Gorbunova and Aslan Tsivadze},
title = {Selective one-step synthesis of triple-decker (porphyrinato) (phthalocyaninato) early lanthanides: The balance of concurrent processes},
journal = {Dalton Transactions},
year = {2011},
volume = {40},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://xlink.rsc.org/?DOI=c1dt11141h},
number = {43},
pages = {11539--11549},
doi = {10.1039/c1dt11141h}
}
Cite this
MLA
Copy
Birin, Kirill P., et al. “Selective one-step synthesis of triple-decker (porphyrinato) (phthalocyaninato) early lanthanides: The balance of concurrent processes.” Dalton Transactions, vol. 40, no. 43, Sep. 2011, pp. 11539-11549. https://xlink.rsc.org/?DOI=c1dt11141h.