NMR investigation of intramolecular dynamics of heteroleptic triple-decker (porphyrinato)(phthalocyaninato) lanthanides
Тип публикации: Journal Article
Дата публикации: 2011-09-20
scimago Q2
wos Q1
БС1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
21931915
Inorganic Chemistry
Краткое описание
Intramolecular dynamics of meso-aryl substituents of porphyrin deck in the triple-decker lanthanide (porphyrinato)(phthalocyaninates) of symmetrical type [Br(4)TPP]Ln[(15C5)(4)Pc]Ln[Br(4)TPP] (Ln = La, Nd, Eu; [Br(4)TPP] = tetrakis-5,10,15,20-(4-bromophenyl)-porphyrinato-ligand; [(15C5)(4)Pc] = tetrakis-(15-crown-5)-phthalocyaninato-ligand) are investigated. Attempts to achieve coalescence were not successful, although the trend of exchanging protons to coalescence point was observed in the case of Nd and Eu complexes. The analysis of NOESY cross-peaks between exchanging protons allowed to evaluate the rotation rate constants at different temperatures. The activation barrier of the meso-aryl substituent rotation was calculated with Arrhenius equation based on determined rate constants. The rate constants are lower and activation barriers are higher than ones found previously for related compounds.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Топ-30
Журналы
|
1
2
3
|
|
|
Inorganic Chemistry
3 публикации, 20%
|
|
|
Journal of Porphyrins and Phthalocyanines
2 публикации, 13.33%
|
|
|
Dalton Transactions
2 публикации, 13.33%
|
|
|
Molecules
2 публикации, 13.33%
|
|
|
Russian Journal of Inorganic Chemistry
1 публикация, 6.67%
|
|
|
Dyes and Pigments
1 публикация, 6.67%
|
|
|
Chemistry Letters
1 публикация, 6.67%
|
|
|
Russian Chemical Reviews
1 публикация, 6.67%
|
|
|
Sensors and Actuators, B: Chemical
1 публикация, 6.67%
|
|
|
Chemistry - A European Journal
1 публикация, 6.67%
|
|
|
1
2
3
|
Издатели
|
1
2
3
|
|
|
American Chemical Society (ACS)
3 публикации, 20%
|
|
|
Elsevier
2 публикации, 13.33%
|
|
|
World Scientific
2 публикации, 13.33%
|
|
|
Royal Society of Chemistry (RSC)
2 публикации, 13.33%
|
|
|
MDPI
2 публикации, 13.33%
|
|
|
Pleiades Publishing
1 публикация, 6.67%
|
|
|
Oxford University Press
1 публикация, 6.67%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 публикация, 6.67%
|
|
|
Wiley
1 публикация, 6.67%
|
|
|
1
2
3
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
15
Всего цитирований:
15
Цитирований c 2025:
1
(6.67%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
Birin K. P. et al. NMR investigation of intramolecular dynamics of heteroleptic triple-decker (porphyrinato)(phthalocyaninato) lanthanides // Dalton Transactions. 2011. Vol. 40. No. 43. pp. 11474-11479.
ГОСТ со всеми авторами (до 50)
Скопировать
Birin K. P., Gorbunova Y. G., Tsivadze A. NMR investigation of intramolecular dynamics of heteroleptic triple-decker (porphyrinato)(phthalocyaninato) lanthanides // Dalton Transactions. 2011. Vol. 40. No. 43. pp. 11474-11479.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1039/c1dt11231g
UR - https://xlink.rsc.org/?DOI=c1dt11231g
TI - NMR investigation of intramolecular dynamics of heteroleptic triple-decker (porphyrinato)(phthalocyaninato) lanthanides
T2 - Dalton Transactions
AU - Birin, Kirill P.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan
PY - 2011
DA - 2011/09/20
PB - Royal Society of Chemistry (RSC)
SP - 11474-11479
IS - 43
VL - 40
PMID - 21931915
SN - 1477-9226
SN - 1477-9234
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2011_Birin,
author = {Kirill P. Birin and Yulia G. Gorbunova and Aslan Tsivadze},
title = {NMR investigation of intramolecular dynamics of heteroleptic triple-decker (porphyrinato)(phthalocyaninato) lanthanides},
journal = {Dalton Transactions},
year = {2011},
volume = {40},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://xlink.rsc.org/?DOI=c1dt11231g},
number = {43},
pages = {11474--11479},
doi = {10.1039/c1dt11231g}
}
Цитировать
MLA
Скопировать
Birin, Kirill P., et al. “NMR investigation of intramolecular dynamics of heteroleptic triple-decker (porphyrinato)(phthalocyaninato) lanthanides.” Dalton Transactions, vol. 40, no. 43, Sep. 2011, pp. 11474-11479. https://xlink.rsc.org/?DOI=c1dt11231g.
Лаборатории