Chemical Communications

, том 48 , издание 89 , страницы 10963

Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands

Тип публикации: Journal Article

Дата публикации: 2012-09-19

Royal Society of Chemistry (RSC)

Chemical Communications

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WOS Q2

БС1

SJR: 0.907

CiteScore: 7.2

Impact factor: 4.3

ISSN: 13597345, 1364548X

DOI: 10.1039/c2cc35869g

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PubMed ID: 23034569

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

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The first metal coordination complex of a radical ligand based on the 1,2,3-dithiazolyl heterocycle is reported. 6,7-Dimethyl-1,4-dioxo-naphtho[2,3-d][1,2,3]dithiazolyl acts as a bridging ligand in the volatile trinuclear Mn(hfac)(2)-Rad-Mn(hfac)(2)-Rad-Mn(hfac)(2) complex (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-). The Mn(II) and radical ligand spins are coupled anti-ferromagnetically (AF) resulting in an S(T) = 13/2 spin ground state.

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SULLIVAN D. et al. Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands // Chemical Communications. 2012. Vol. 48. No. 89. p. 10963.

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SULLIVAN D., Clerac R., Jennings M. R., Lough A. J., Preuss K. E. Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands // Chemical Communications. 2012. Vol. 48. No. 89. p. 10963.

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TY - JOUR

DO - 10.1039/c2cc35869g

UR - https://doi.org/10.1039/c2cc35869g

TI - Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands

T2 - Chemical Communications

AU - SULLIVAN, David J.

AU - Clerac, Rodolphe

AU - Jennings, M. R.

AU - Lough, Alan J.

AU - Preuss, Kathryn E.

PY - 2012

DA - 2012/09/19

PB - Royal Society of Chemistry (RSC)

SP - 10963

IS - 89

VL - 48

PMID - 23034569

SN - 1359-7345

SN - 1364-548X

ER -

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@article{2012_SULLIVAN,

author = {David J. SULLIVAN and Rodolphe Clerac and M. R. Jennings and Alan J. Lough and Kathryn E. Preuss},

title = {Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands},

journal = {Chemical Communications},

year = {2012},

volume = {48},

publisher = {Royal Society of Chemistry (RSC)},

month = {sep},

url = {https://doi.org/10.1039/c2cc35869g},

number = {89},

pages = {10963},

doi = {10.1039/c2cc35869g}

}

MLA

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SULLIVAN, David J., et al. “Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands.” Chemical Communications, vol. 48, no. 89, Sep. 2012, p. 10963. https://doi.org/10.1039/c2cc35869g.

Издатель

Royal Society of Chemistry (RSC)

Журнал

Chemical Communications

SCImago Q1

WOS Q2

БС1