Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands
2
CNRS, CRPP, UPR 8641, F-33600 Pessac, France
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4
185 Chelsea Avenue, London, ON, Canada
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Publication type: Journal Article
Publication date: 2012-09-19
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
23034569
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The first metal coordination complex of a radical ligand based on the 1,2,3-dithiazolyl heterocycle is reported. 6,7-Dimethyl-1,4-dioxo-naphtho[2,3-d][1,2,3]dithiazolyl acts as a bridging ligand in the volatile trinuclear Mn(hfac)(2)-Rad-Mn(hfac)(2)-Rad-Mn(hfac)(2) complex (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-). The Mn(II) and radical ligand spins are coupled anti-ferromagnetically (AF) resulting in an S(T) = 13/2 spin ground state.
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Total citations:
19
Citations from 2024:
3
(15.79%)
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GOST
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SULLIVAN D. et al. Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands // Chemical Communications. 2012. Vol. 48. No. 89. p. 10963.
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SULLIVAN D., Clerac R., Jennings M. R., Lough A. J., Preuss K. E. Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands // Chemical Communications. 2012. Vol. 48. No. 89. p. 10963.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c2cc35869g
UR - https://doi.org/10.1039/c2cc35869g
TI - Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands
T2 - Chemical Communications
AU - SULLIVAN, David J.
AU - Clerac, Rodolphe
AU - Jennings, M. R.
AU - Lough, Alan J.
AU - Preuss, Kathryn E.
PY - 2012
DA - 2012/09/19
PB - Royal Society of Chemistry (RSC)
SP - 10963
IS - 89
VL - 48
PMID - 23034569
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_SULLIVAN,
author = {David J. SULLIVAN and Rodolphe Clerac and M. R. Jennings and Alan J. Lough and Kathryn E. Preuss},
title = {Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands},
journal = {Chemical Communications},
year = {2012},
volume = {48},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://doi.org/10.1039/c2cc35869g},
number = {89},
pages = {10963},
doi = {10.1039/c2cc35869g}
}
Cite this
MLA
Copy
SULLIVAN, David J., et al. “Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands.” Chemical Communications, vol. 48, no. 89, Sep. 2012, p. 10963. https://doi.org/10.1039/c2cc35869g.
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