Chemical Society Reviews, volume 42, issue 18, pages 7521

On the mechanochemical activation by ultrasound

Emanuela Calcio Gaudino 1
2
 
Departamento de Química Orgánica e Inorgánica, Facultad de Ciencias-UEX, Avda. de Elvas s/n, E-06006 Badajoz, Spain
Publication typeJournal Article
Publication date2013-01-15
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor46.2
ISSN03060012, 14604744
General Chemistry
Abstract
Chemists have discovered, and recently actively exploited, the fact that subjecting certain molecules to ultrasound waves can bring about transformations that give insight into the correlation between classical tribological processes and the mechanical action caused by collapsing microbubbles when sonic waves propagate through a liquid medium. Chemical transformations induced by ultrasound take place in solution via mechanisms that are markedly different from those associated with molecular activation in the solid state. Both fields, however, share some striking similarities and numerous sonochemical reactions can be rationalized in purely mechanical terms. This tutorial review examines the tribochemical interpretation of sonochemical reactivity and how the multifaceted action of cavitational phenomena determines molecular evolution. A series of case studies involving solids, crystals, and polymers illustrate the mechanical properties of sound waves.

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GOST |
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GOST Copy
Cravotto G., Calcio Gaudino E., Cintas P. On the mechanochemical activation by ultrasound // Chemical Society Reviews. 2013. Vol. 42. No. 18. p. 7521.
GOST all authors (up to 50) Copy
Cravotto G., Calcio Gaudino E., Cintas P. On the mechanochemical activation by ultrasound // Chemical Society Reviews. 2013. Vol. 42. No. 18. p. 7521.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c2cs35456j
UR - https://doi.org/10.1039/c2cs35456j
TI - On the mechanochemical activation by ultrasound
T2 - Chemical Society Reviews
AU - Calcio Gaudino, Emanuela
AU - Cintas, Pedro
AU - Cravotto, Giancarlo
PY - 2013
DA - 2013/01/15 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 7521
IS - 18
VL - 42
SN - 0306-0012
SN - 1460-4744
ER -
BibTex |
Cite this
BibTex Copy
@article{2013_Cravotto,
author = {Emanuela Calcio Gaudino and Pedro Cintas and Giancarlo Cravotto},
title = {On the mechanochemical activation by ultrasound},
journal = {Chemical Society Reviews},
year = {2013},
volume = {42},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c2cs35456j},
number = {18},
pages = {7521},
doi = {10.1039/c2cs35456j}
}
MLA
Cite this
MLA Copy
Cravotto, Giancarlo, et al. “On the mechanochemical activation by ultrasound.” Chemical Society Reviews, vol. 42, no. 18, Jan. 2013, p. 7521. https://doi.org/10.1039/c2cs35456j.
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