Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru)
Publication type: Journal Article
Publication date: 2012-04-26
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
22539456
Inorganic Chemistry
Abstract
The synthesis, activation, and heats of CO(2) adsorption for the known members of the M(3)(BTC)(2) (HKUST-1) isostructural series (M = Cr, Fe, Ni, Zn, Ni, Cu, Mo) were investigated to gain insight into the impact of CO(2)-metal interactions for CO(2) storage/separation applications. With the use of modified syntheses and activation procedures, improved BET surface areas were obtained for M = Ni, Mo, and Ru. The zero-coverage isosteric heats of CO(2) adsorption were measured for the Cu, Cr, Ni, Mo, and Ru analogues and gave values consistent with those reported for MOFs containing coordinatively unsaturated metal sites, but lower than for amine functionalized materials. Notably, the Ni and Ru congeners exhibited the highest CO(2) affinities in the studied series. These behaviors were attributed to the presence of residual guest molecules in the case of Ni(3)(BTC)(2)(Me(2)NH)(2)(H(2)O) and the increased charge of the dimetal secondary building unit in [Ru(3)(BTC)(2)][BTC](0.5).
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Wade C. R., Dincă M. Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru) // Dalton Transactions. 2012. Vol. 41. No. 26. p. 7931.
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Wade C. R., Dincă M. Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru) // Dalton Transactions. 2012. Vol. 41. No. 26. p. 7931.
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TY - JOUR
DO - 10.1039/c2dt30372h
UR - https://doi.org/10.1039/c2dt30372h
TI - Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru)
T2 - Dalton Transactions
AU - Wade, Casey R
AU - Dincă, Mircea
PY - 2012
DA - 2012/04/26
PB - Royal Society of Chemistry (RSC)
SP - 7931
IS - 26
VL - 41
PMID - 22539456
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2012_Wade,
author = {Casey R Wade and Mircea Dincă},
title = {Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru)},
journal = {Dalton Transactions},
year = {2012},
volume = {41},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://doi.org/10.1039/c2dt30372h},
number = {26},
pages = {7931},
doi = {10.1039/c2dt30372h}
}
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Wade, Casey R., and Mircea Dincă. “Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru).” Dalton Transactions, vol. 41, no. 26, Apr. 2012, p. 7931. https://doi.org/10.1039/c2dt30372h.