volume 42 issue 20 pages 7345

Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki–Miyaura reactions

Thibault E Schmid 1
Dale C Jones 1
Olivier Songis 1
Olivier Diebolt 1
Marc R L Furst 1
Publication typeJournal Article
Publication date2013-01-07
scimago Q2
wos Q1
SJR0.653
CiteScore6.0
Impact factor3.3
ISSN14779226, 14779234
PubMed ID:  23348096
Inorganic Chemistry
Abstract
A series of N-heterocyclic carbene (NHC)/PR3 palladium(II) and palladium(0) complexes has been synthesized and fully characterized. X-ray crystallographic data have allowed comparison of ligand steric properties. The NHC ligand was found to vary its steric properties as a function of the phosphine co-ligand. These complexes display interesting catalytic properties in the Suzuki-Miyaura reaction performed in aqueous media. The pre-catalyst [PdCl2(IPr)(XPhos)] (IPr = N,N'-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene; XPhos = 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl) was found to be the most efficient system, promoting the coupling of a wide range of aryl chlorides with boronic acids in aqueous media with a typical catalyst loading of 0.03 mol%.
Found 
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Schmid T. E. et al. Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki–Miyaura reactions // Dalton Transactions. 2013. Vol. 42. No. 20. p. 7345.
GOST all authors (up to 50) Copy
Schmid T. E., Jones D. C., Songis O., Diebolt O., Furst M. R. L., Slawin A. M. Z., Cazin C. S. J. Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki–Miyaura reactions // Dalton Transactions. 2013. Vol. 42. No. 20. p. 7345.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c2dt32858e
UR - https://doi.org/10.1039/c2dt32858e
TI - Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki–Miyaura reactions
T2 - Dalton Transactions
AU - Schmid, Thibault E
AU - Jones, Dale C
AU - Songis, Olivier
AU - Diebolt, Olivier
AU - Furst, Marc R L
AU - Slawin, Alexandra M. Z.
AU - Cazin, Catherine S. J.
PY - 2013
DA - 2013/01/07
PB - Royal Society of Chemistry (RSC)
SP - 7345
IS - 20
VL - 42
PMID - 23348096
SN - 1477-9226
SN - 1477-9234
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Schmid,
author = {Thibault E Schmid and Dale C Jones and Olivier Songis and Olivier Diebolt and Marc R L Furst and Alexandra M. Z. Slawin and Catherine S. J. Cazin},
title = {Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki–Miyaura reactions},
journal = {Dalton Transactions},
year = {2013},
volume = {42},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c2dt32858e},
number = {20},
pages = {7345},
doi = {10.1039/c2dt32858e}
}
MLA
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MLA Copy
Schmid, Thibault E., et al. “Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki–Miyaura reactions.” Dalton Transactions, vol. 42, no. 20, Jan. 2013, p. 7345. https://doi.org/10.1039/c2dt32858e.