Metal–organic frameworks for visible light absorption via anion substitution
Тип публикации: Journal Article
Дата публикации: 2012-02-22
scimago Q1
wos Q1
БС1
SJR: 2.462
CiteScore: 16.7
Impact factor: 9.5
ISSN: 20507488, 20507496, 09599428, 13645501
Materials Chemistry
General Chemistry
Краткое описание
We report that the band gap of metal–organic frameworks (MOFs) could be tuned to absorb visible light via anion substitution. First of all, when an oxygen anion in the metal oxide core of IRMOF-1 is substituted with sulphur anions as Zn4S or selenium anions as Zn4Se to form IRMOF-1-S and IRMOF-1-Se, respectively, they result in density-of-states and molecular orbitals for the band gap that can utilize visible light through shifting of the Fermi level due to their electron-rich properties. This implies that the tailored band gap could provide a new route to allow the series of IRMOFs and other MOFs to be used for visible light absorption.
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ГОСТ
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Choi J. et al. Metal–organic frameworks for visible light absorption via anion substitution // Journal of Materials Chemistry A. 2012. Vol. 22. No. 20. p. 10144.
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Choi J., Jung Hoon Choi, Jeon H. J., Choi K. H., Kang J. K. Metal–organic frameworks for visible light absorption via anion substitution // Journal of Materials Chemistry A. 2012. Vol. 22. No. 20. p. 10144.
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TY - JOUR
DO - 10.1039/c2jm16245h
UR - https://doi.org/10.1039/c2jm16245h
TI - Metal–organic frameworks for visible light absorption via anion substitution
T2 - Journal of Materials Chemistry A
AU - Choi, Jung-Hoon
AU - Jung Hoon Choi
AU - Jeon, Hyung Joon
AU - Choi, Kyung Hyun
AU - Kang, Jeung Ku
PY - 2012
DA - 2012/02/22
PB - Royal Society of Chemistry (RSC)
SP - 10144
IS - 20
VL - 22
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
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@article{2012_Choi,
author = {Jung-Hoon Choi and Jung Hoon Choi and Hyung Joon Jeon and Kyung Hyun Choi and Jeung Ku Kang},
title = {Metal–organic frameworks for visible light absorption via anion substitution},
journal = {Journal of Materials Chemistry A},
year = {2012},
volume = {22},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039/c2jm16245h},
number = {20},
pages = {10144},
doi = {10.1039/c2jm16245h}
}
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MLA
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Choi, Jung-Hoon, et al. “Metal–organic frameworks for visible light absorption via anion substitution.” Journal of Materials Chemistry A, vol. 22, no. 20, Feb. 2012, p. 10144. https://doi.org/10.1039/c2jm16245h.