volume 10 issue 10 pages 2139

Synthesis of pyrrolyldipyrrinato BF2 complexes by oxidative nucleophilic substitution of boron dipyrromethene with pyrrole

Publication typeJournal Article
Publication date2012-01-01
scimago Q2
wos Q2
SJR0.600
CiteScore5.2
Impact factor2.7
ISSN14770520, 14770539
PubMed ID:  22302220
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Direct oxidative nucleophilic substitution of the 3-hydrogen of BODIPY dyes by pyrrole has been developed under reflux condition under oxygen, from which a series of pyrrolyldipyrrinato BF(2) complexes 1a-h, as extended BODIPYs, have been synthesized. Most of these BODIPYs show strong fluorescence emissions at wavelengths over 600 nm in six solvents of different polarity. Removal of the BF(2) group from BODIPY 1e gave the corresponding free base pyrrolyldipyrrin 7 as an analog of the natural product prodigiosin, in high yield.
Found 
Found 

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GOST |
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GOST Copy
Zhang M. et al. Synthesis of pyrrolyldipyrrinato BF2 complexes by oxidative nucleophilic substitution of boron dipyrromethene with pyrrole // Organic and Biomolecular Chemistry. 2012. Vol. 10. No. 10. p. 2139.
GOST all authors (up to 50) Copy
Zhang M., Hao E., Zhou J., Yu C., Bai G., Wang F., Jiao L. Synthesis of pyrrolyldipyrrinato BF2 complexes by oxidative nucleophilic substitution of boron dipyrromethene with pyrrole // Organic and Biomolecular Chemistry. 2012. Vol. 10. No. 10. p. 2139.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c2ob06689k
UR - https://doi.org/10.1039/c2ob06689k
TI - Synthesis of pyrrolyldipyrrinato BF2 complexes by oxidative nucleophilic substitution of boron dipyrromethene with pyrrole
T2 - Organic and Biomolecular Chemistry
AU - Zhang, Min
AU - Hao, Erhong
AU - Zhou, Jinyuan
AU - Yu, Changjiang
AU - Bai, Guifeng
AU - Wang, Fengyun
AU - Jiao, Lijuan
PY - 2012
DA - 2012/01/01
PB - Royal Society of Chemistry (RSC)
SP - 2139
IS - 10
VL - 10
PMID - 22302220
SN - 1477-0520
SN - 1477-0539
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2012_Zhang,
author = {Min Zhang and Erhong Hao and Jinyuan Zhou and Changjiang Yu and Guifeng Bai and Fengyun Wang and Lijuan Jiao},
title = {Synthesis of pyrrolyldipyrrinato BF2 complexes by oxidative nucleophilic substitution of boron dipyrromethene with pyrrole},
journal = {Organic and Biomolecular Chemistry},
year = {2012},
volume = {10},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c2ob06689k},
number = {10},
pages = {2139},
doi = {10.1039/c2ob06689k}
}
MLA
Cite this
MLA Copy
Zhang, Min, et al. “Synthesis of pyrrolyldipyrrinato BF2 complexes by oxidative nucleophilic substitution of boron dipyrromethene with pyrrole.” Organic and Biomolecular Chemistry, vol. 10, no. 10, Jan. 2012, p. 2139. https://doi.org/10.1039/c2ob06689k.