Selective reduction of condensed N-heterocycles using water as a solvent and a hydrogen source
Publication type: Journal Article
Publication date: 2013-01-01
scimago Q2
wos Q2
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
23313913
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The reduction of unprotected indoles and quinolines is described using water as a hydrogen source. The method is based on the application of a RANEY® type Ni-Al alloy in an aqueous medium. During the reaction the Al content of the alloy, used as reductants, reacts with water in situ providing hydrogen and a RANEY® Ni catalyst, thus the alloy serves as a hydrogen generator as well as a hydrogenation catalyst. The simplicity and efficacy of the method are illustrated by the selective reduction of a variety of substituted indoles and quinolines to indolines and tetrahydroquinolines, respectively.
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33
Total citations:
33
Citations from 2024:
4
(12.12%)
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GOST
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Cho H. et al. Selective reduction of condensed N-heterocycles using water as a solvent and a hydrogen source // Organic and Biomolecular Chemistry. 2013. Vol. 11. No. 7. p. 1209.
GOST all authors (up to 50)
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Cho H., Fanni T., Török F., Torok B. Selective reduction of condensed N-heterocycles using water as a solvent and a hydrogen source // Organic and Biomolecular Chemistry. 2013. Vol. 11. No. 7. p. 1209.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c2ob26903a
UR - https://doi.org/10.1039/c2ob26903a
TI - Selective reduction of condensed N-heterocycles using water as a solvent and a hydrogen source
T2 - Organic and Biomolecular Chemistry
AU - Cho, Hyejin
AU - Fanni, Torok
AU - Török, Fanni
AU - Torok, Bela
PY - 2013
DA - 2013/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1209
IS - 7
VL - 11
PMID - 23313913
SN - 1477-0520
SN - 1477-0539
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Cho,
author = {Hyejin Cho and Torok Fanni and Fanni Török and Bela Torok},
title = {Selective reduction of condensed N-heterocycles using water as a solvent and a hydrogen source},
journal = {Organic and Biomolecular Chemistry},
year = {2013},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c2ob26903a},
number = {7},
pages = {1209},
doi = {10.1039/c2ob26903a}
}
Cite this
MLA
Copy
Cho, Hyejin, et al. “Selective reduction of condensed N-heterocycles using water as a solvent and a hydrogen source.” Organic and Biomolecular Chemistry, vol. 11, no. 7, Jan. 2013, p. 1209. https://doi.org/10.1039/c2ob26903a.