Electronic structure of bis(cyclopentadienyl) lanthanide compounds: photoelectron spectra and molecular orbital calculations
Publication type: Journal Article
Publication date: 1986-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00224936
Molecular Medicine
Abstract
Gas phase He-I and He-II photoelectron (p.e.) spectra have been obtained for Ln(η-C5Me5)2, where Ln = Sm, Eu, Yb, and bands associated with ionization of f-electrons are identified for the Sm and Yb compounds; ionization energies calculated from quasi-relativistic Xα-SW calculations are in good agreement with the experimental values showing the compounds to be highly ionic in nature, but providing no orbital reason for the established non-parallel geometry of the rings.
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34
Total citations:
34
Citations from 2025:
1
(2.94%)
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Andersen R. A. et al. Electronic structure of bis(cyclopentadienyl) lanthanide compounds: photoelectron spectra and molecular orbital calculations // Journal of the Chemical Society Chemical Communications. 1986. Vol. 5. pp. 405-407.
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Andersen R. A., Boncella J., Burns C., Green J. B., Hohl D., Rösch N. Electronic structure of bis(cyclopentadienyl) lanthanide compounds: photoelectron spectra and molecular orbital calculations // Journal of the Chemical Society Chemical Communications. 1986. Vol. 5. pp. 405-407.
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TY - JOUR
DO - 10.1039/c39860000405
UR - https://doi.org/10.1039/c39860000405
TI - Electronic structure of bis(cyclopentadienyl) lanthanide compounds: photoelectron spectra and molecular orbital calculations
T2 - Journal of the Chemical Society Chemical Communications
AU - Andersen, Richard A.
AU - Boncella, James
AU - Burns, Carol M.
AU - Green, Jennifer B.
AU - Hohl, Detlef
AU - Rösch, Notker
PY - 1986
DA - 1986/01/01
PB - Royal Society of Chemistry (RSC)
SP - 405-407
IS - 5
SN - 0022-4936
ER -
Cite this
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@article{1986_Andersen,
author = {Richard A. Andersen and James Boncella and Carol M. Burns and Jennifer B. Green and Detlef Hohl and Notker Rösch},
title = {Electronic structure of bis(cyclopentadienyl) lanthanide compounds: photoelectron spectra and molecular orbital calculations},
journal = {Journal of the Chemical Society Chemical Communications},
year = {1986},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c39860000405},
number = {5},
pages = {405--407},
doi = {10.1039/c39860000405}
}