Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine.
Publication type: Journal Article
Publication date: 2013-06-27
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
23863949
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
A key intermediate, difluoromethylene phosphobetaine, in the Wittig reaction of ClCF2CO2Na-Ph3P with aldehydes was synthesized and characterized, which confirmed the reaction mechanism. The decarboxylation of this stable intermediate was a convenient approach for Wittig difluroolefination. Its reactivity could be adjusted by the modification of the substituent on the phosphorus.
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247
Total citations:
247
Citations from 2025:
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(9.31%)
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GOST
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Zheng J. et al. Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine. // Chemical Communications. 2013. Vol. 49. No. 68. p. 7513.
GOST all authors (up to 50)
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Zheng J., Ji C., Lin J., Guo Y., Xiao J. Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine. // Chemical Communications. 2013. Vol. 49. No. 68. p. 7513.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c3cc44271c
UR - https://doi.org/10.1039/c3cc44271c
TI - Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine.
T2 - Chemical Communications
AU - Zheng, Jian
AU - Ji, Cai
AU - Lin, Jintong
AU - Guo, Yong
AU - Xiao, Jichang
PY - 2013
DA - 2013/06/27
PB - Royal Society of Chemistry (RSC)
SP - 7513
IS - 68
VL - 49
PMID - 23863949
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Zheng,
author = {Jian Zheng and Cai Ji and Jintong Lin and Yong Guo and Jichang Xiao},
title = {Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine.},
journal = {Chemical Communications},
year = {2013},
volume = {49},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://doi.org/10.1039/c3cc44271c},
number = {68},
pages = {7513},
doi = {10.1039/c3cc44271c}
}
Cite this
MLA
Copy
Zheng, Jian, et al. “Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine..” Chemical Communications, vol. 49, no. 68, Jun. 2013, p. 7513. https://doi.org/10.1039/c3cc44271c.