Green Chemistry, volume 15, issue 11, pages 3083
High activity and switchable selectivity in the synthesis of cyclic and polymeric cyclohexene carbonates with iron amino triphenolate catalysts
Masoumeh Taherimehr
1
,
Syed M Al Amsyar
1
,
Syed M Al-Amsyar
1
,
Christopher J Whiteoak
2
,
Arjan W Kleij
2, 3
,
Paolo P. Pescarmona
1
2
Publication type: Journal Article
Publication date: 2013-08-27
Journal:
Green Chemistry
Q1
Q1
SJR: 1.878
CiteScore: 16.1
Impact factor: 9.3
ISSN: 14639262, 14639270
Environmental Chemistry
Pollution
Abstract
Iron(III) amino triphenolate complexes were studied as catalysts for the reaction of carbon dioxide (CO2) with cyclohexene oxide, which can lead to the formation of cyclic carbonate and/or polycarbonate products. Both types of compound are relevant, but for their practical application it is crucial to be able to control the selectivity of the reaction. By working under solvent-free, green conditions with CO2 in the supercritical state and by tailoring the nature and the relative amount of the co-catalyst (Bu4NX or PPNX, where X is a halide) used in combination with the iron(III) complex, we have been able to enhance the catalytic efficiency and achieve a selective and high-yield synthesis of either the cyclic or the polymeric product. The studied reaction is relevant in the context of green chemistry as it provides an atom-efficient route for the conversion of CO2, which is an inexpensive, widely available, renewable and non-toxic feedstock, into valuable products.
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GOST
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Taherimehr M. et al. High activity and switchable selectivity in the synthesis of cyclic and polymeric cyclohexene carbonates with iron amino triphenolate catalysts // Green Chemistry. 2013. Vol. 15. No. 11. p. 3083.
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Taherimehr M., Al Amsyar S. M., Al-Amsyar S. M., Whiteoak C. J., Kleij A. W., Pescarmona P. P. High activity and switchable selectivity in the synthesis of cyclic and polymeric cyclohexene carbonates with iron amino triphenolate catalysts // Green Chemistry. 2013. Vol. 15. No. 11. p. 3083.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c3gc41303a
UR - https://doi.org/10.1039/c3gc41303a
TI - High activity and switchable selectivity in the synthesis of cyclic and polymeric cyclohexene carbonates with iron amino triphenolate catalysts
T2 - Green Chemistry
AU - Taherimehr, Masoumeh
AU - Al Amsyar, Syed M
AU - Al-Amsyar, Syed M
AU - Whiteoak, Christopher J
AU - Kleij, Arjan W
AU - Pescarmona, Paolo P.
PY - 2013
DA - 2013/08/27
PB - Royal Society of Chemistry (RSC)
SP - 3083
IS - 11
VL - 15
SN - 1463-9262
SN - 1463-9270
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Taherimehr,
author = {Masoumeh Taherimehr and Syed M Al Amsyar and Syed M Al-Amsyar and Christopher J Whiteoak and Arjan W Kleij and Paolo P. Pescarmona},
title = {High activity and switchable selectivity in the synthesis of cyclic and polymeric cyclohexene carbonates with iron amino triphenolate catalysts},
journal = {Green Chemistry},
year = {2013},
volume = {15},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039/c3gc41303a},
number = {11},
pages = {3083},
doi = {10.1039/c3gc41303a}
}
Cite this
MLA
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Taherimehr, Masoumeh, et al. “High activity and switchable selectivity in the synthesis of cyclic and polymeric cyclohexene carbonates with iron amino triphenolate catalysts.” Green Chemistry, vol. 15, no. 11, Aug. 2013, p. 3083. https://doi.org/10.1039/c3gc41303a.
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