Open Access
Switching the anisotropy barrier of a single-ion magnet by symmetry change from quasi-D5h to quasi-Oh
Jun-Liang Liu
1
,
Yancong Chen
1
,
Yanzhen Zheng
2
,
Weiquan W Lin
1
,
Liviu Ungur
3
,
L.F. Chibotaru
3
,
Mingliang Tong
1
Publication type: Journal Article
Publication date: 2013-06-10
scimago Q1
wos Q1
SJR: 2.138
CiteScore: 12.6
Impact factor: 7.4
ISSN: 20416520, 20416539
General Chemistry
Abstract
A reversible single-crystal-to-single-crystal transformation is used to dramatically change the relaxation behavior of a single-ion magnet. The coordination geometry of the DyIII site of a [Zn–Dy–Zn] complex changes from pentagonal–bipyramid (quasi-D5h) to octahedron (quasi-Oh), inducing an energy barrier change from 305 cm−1 (439 K) to a negligible value, respectively. Ab initio calculations reveal that the ideal D5h–DyIII is of perfect axiality with a substantial energy barrier in accordance with the experimental result.
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504
Total citations:
504
Citations from 2025:
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(4.76%)
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GOST
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Liu J. et al. Switching the anisotropy barrier of a single-ion magnet by symmetry change from quasi-D5h to quasi-Oh // Chemical Science. 2013. Vol. 4. No. 8. p. 3310.
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Liu J., Chen Y., Zheng Y., Lin W. W., Ungur L., Wernsdorfer W., Chibotaru L., Tong M. Switching the anisotropy barrier of a single-ion magnet by symmetry change from quasi-D5h to quasi-Oh // Chemical Science. 2013. Vol. 4. No. 8. p. 3310.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c3sc50843a
UR - https://doi.org/10.1039/c3sc50843a
TI - Switching the anisotropy barrier of a single-ion magnet by symmetry change from quasi-D5h to quasi-Oh
T2 - Chemical Science
AU - Liu, Jun-Liang
AU - Chen, Yancong
AU - Zheng, Yanzhen
AU - Lin, Weiquan W
AU - Ungur, Liviu
AU - Wernsdorfer, Wolfgang
AU - Chibotaru, L.F.
AU - Tong, Mingliang
PY - 2013
DA - 2013/06/10
PB - Royal Society of Chemistry (RSC)
SP - 3310
IS - 8
VL - 4
SN - 2041-6520
SN - 2041-6539
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Liu,
author = {Jun-Liang Liu and Yancong Chen and Yanzhen Zheng and Weiquan W Lin and Liviu Ungur and Wolfgang Wernsdorfer and L.F. Chibotaru and Mingliang Tong},
title = {Switching the anisotropy barrier of a single-ion magnet by symmetry change from quasi-D5h to quasi-Oh},
journal = {Chemical Science},
year = {2013},
volume = {4},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://doi.org/10.1039/c3sc50843a},
number = {8},
pages = {3310},
doi = {10.1039/c3sc50843a}
}
Cite this
MLA
Copy
Liu, Jun-Liang, et al. “Switching the anisotropy barrier of a single-ion magnet by symmetry change from quasi-D5h to quasi-Oh.” Chemical Science, vol. 4, no. 8, Jun. 2013, p. 3310. https://doi.org/10.1039/c3sc50843a.