volume 50 issue 84 pages 12753-12756

Bypassing a highly unstable frustrated Lewis pair: dihydrogen cleavage by a thermally robust silylium–phosphine adduct

Thomas J Herrington 1
Bryan K. Ward 1
Laurence R Doyle 1
Joe McDermott 1
Andrew C White 1
Patricia A Hunt 1
Publication typeJournal Article
Publication date2014-08-26
scimago Q1
wos Q2
SJR1.037
CiteScore7.4
Impact factor4.2
ISSN13597345, 1364548X
PubMed ID:  25204297
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract

The thermally robust silylium complex [iPr3Si–PtBu3]+[B(C6F5)4] (1) activates H2/D2 at 90 °C (PhCl). However, experimental evidence and DFT calculations show no evidence for dissociation into the separated Lewis pair.

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GOST Copy
Herrington T. J. et al. Bypassing a highly unstable frustrated Lewis pair: dihydrogen cleavage by a thermally robust silylium–phosphine adduct // Chemical Communications. 2014. Vol. 50. No. 84. pp. 12753-12756.
GOST all authors (up to 50) Copy
Herrington T. J., Ward B. K., Doyle L. R., McDermott J., White A. C., Hunt P. A., Ashley A. Bypassing a highly unstable frustrated Lewis pair: dihydrogen cleavage by a thermally robust silylium–phosphine adduct // Chemical Communications. 2014. Vol. 50. No. 84. pp. 12753-12756.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c4cc05905k
UR - https://doi.org/10.1039/c4cc05905k
TI - Bypassing a highly unstable frustrated Lewis pair: dihydrogen cleavage by a thermally robust silylium–phosphine adduct
T2 - Chemical Communications
AU - Herrington, Thomas J
AU - Ward, Bryan K.
AU - Doyle, Laurence R
AU - McDermott, Joe
AU - White, Andrew C
AU - Hunt, Patricia A
AU - Ashley, Andrew
PY - 2014
DA - 2014/08/26
PB - Royal Society of Chemistry (RSC)
SP - 12753-12756
IS - 84
VL - 50
PMID - 25204297
SN - 1359-7345
SN - 1364-548X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Herrington,
author = {Thomas J Herrington and Bryan K. Ward and Laurence R Doyle and Joe McDermott and Andrew C White and Patricia A Hunt and Andrew Ashley},
title = {Bypassing a highly unstable frustrated Lewis pair: dihydrogen cleavage by a thermally robust silylium–phosphine adduct},
journal = {Chemical Communications},
year = {2014},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039/c4cc05905k},
number = {84},
pages = {12753--12756},
doi = {10.1039/c4cc05905k}
}
MLA
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MLA Copy
Herrington, Thomas J., et al. “Bypassing a highly unstable frustrated Lewis pair: dihydrogen cleavage by a thermally robust silylium–phosphine adduct.” Chemical Communications, vol. 50, no. 84, Aug. 2014, pp. 12753-12756. https://doi.org/10.1039/c4cc05905k.
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