volume 43 issue 41 pages 15287-15290

Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics

Michael S Inkpen 1, 2, 3
Andrew C White 1, 2, 3
Tim Albrecht 1, 2, 3
NICHOLAS LONG 1, 2, 3
1
 
DEPARTMENT OF CHEMISTRY
3
 
London SW7 2AZ, UK
Publication typeJournal Article
Publication date2014-08-20
scimago Q2
wos Q1
SJR0.653
CiteScore6.0
Impact factor3.3
ISSN14779226, 14779234
PubMed ID:  25184421
Inorganic Chemistry
Abstract

A much improved route to 1,1′-bis(arylethynyl)ferrocenes comprising accessible thiolates on the aryl ring is reported. Unanticipated reactions between AcCl, TBAF–BBr3 and ferrocenyl-alkynes are also discussed, offering a rationale for previous synthetic difficulties.

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GOST Copy
Inkpen M. S. et al. Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics // Dalton Transactions. 2014. Vol. 43. No. 41. pp. 15287-15290.
GOST all authors (up to 50) Copy
Inkpen M. S., White A. C., Albrecht T., LONG N. Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics // Dalton Transactions. 2014. Vol. 43. No. 41. pp. 15287-15290.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c4dt02359e
UR - https://doi.org/10.1039/c4dt02359e
TI - Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics
T2 - Dalton Transactions
AU - Inkpen, Michael S
AU - White, Andrew C
AU - Albrecht, Tim
AU - LONG, NICHOLAS
PY - 2014
DA - 2014/08/20
PB - Royal Society of Chemistry (RSC)
SP - 15287-15290
IS - 41
VL - 43
PMID - 25184421
SN - 1477-9226
SN - 1477-9234
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Inkpen,
author = {Michael S Inkpen and Andrew C White and Tim Albrecht and NICHOLAS LONG},
title = {Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics},
journal = {Dalton Transactions},
year = {2014},
volume = {43},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039/c4dt02359e},
number = {41},
pages = {15287--15290},
doi = {10.1039/c4dt02359e}
}
MLA
Cite this
MLA Copy
Inkpen, Michael S., et al. “Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics.” Dalton Transactions, vol. 43, no. 41, Aug. 2014, pp. 15287-15290. https://doi.org/10.1039/c4dt02359e.
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