Synthesis and cation distribution in the new bismuth oxyhalides with the Sillén-Aurivillius intergrowth structures
Publication type: Journal Article
Publication date: 2015-10-30
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
26556132
Inorganic Chemistry
Abstract
About 20 new compounds with the Sillén-Aurivillius intergrowth structure, Me(1)Me(2)Bi3Nb2O11X (Me(1) = Pb, Sr, Ba; Me(2) = Ca, Sr, Ba; X = Cl, Br, I), have been prepared. They are composed of stacking of [ANb2O7] perovskite blocks, fluorite-type [M2O2] blocks and halogen sheets. The cation distribution between the fluorite and perovskite layers has been studied for Ba2Bi3Nb2O11I, Ca1.25Sr0.75Bi3Nb2O11Cl, BaCaBi3Nb2O11Br and Sr2Bi3Nb2O11Cl. The smaller Me cations tend to reside in the perovskite block while the larger ones are situated in the fluorite-type block. The distribution of the elements was confirmed for BaCaBi3Nb2O11Br using energy dispersive X-ray analysis combined with scanning transmission electron microscopy (STEM-EDX). An electron diffraction study of this compound reveals a local symmetry lowering caused by weakly correlated rotation of NbO6 octahedra. Based on our findings, we suggest a new stability criterion for mixed-layer structures, which is that net charges of any two consecutive layers do not compensate for each other and only the whole layer sequence is electroneutral.
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Total citations:
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Citations from 2024:
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Charkin D. O. et al. Synthesis and cation distribution in the new bismuth oxyhalides with the Sillén-Aurivillius intergrowth structures // Dalton Transactions. 2015. Vol. 44. No. 47. pp. 20568-20576.
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Charkin D. O., Akinfiev V. S., Alekseeva A. M., Batuk M., Abakumov A. M., Kazakov S. Synthesis and cation distribution in the new bismuth oxyhalides with the Sillén-Aurivillius intergrowth structures // Dalton Transactions. 2015. Vol. 44. No. 47. pp. 20568-20576.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c5dt02620b
UR - https://doi.org/10.1039/c5dt02620b
TI - Synthesis and cation distribution in the new bismuth oxyhalides with the Sillén-Aurivillius intergrowth structures
T2 - Dalton Transactions
AU - Charkin, Dmitri O.
AU - Akinfiev, Victor S
AU - Alekseeva, Anastasia M
AU - Batuk, M.
AU - Abakumov, Artem M.
AU - Kazakov, S.M.
PY - 2015
DA - 2015/10/30
PB - Royal Society of Chemistry (RSC)
SP - 20568-20576
IS - 47
VL - 44
PMID - 26556132
SN - 1477-9226
SN - 1477-9234
ER -
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BibTex (up to 50 authors)
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@article{2015_Charkin,
author = {Dmitri O. Charkin and Victor S Akinfiev and Anastasia M Alekseeva and M. Batuk and Artem M. Abakumov and S.M. Kazakov},
title = {Synthesis and cation distribution in the new bismuth oxyhalides with the Sillén-Aurivillius intergrowth structures},
journal = {Dalton Transactions},
year = {2015},
volume = {44},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://doi.org/10.1039/c5dt02620b},
number = {47},
pages = {20568--20576},
doi = {10.1039/c5dt02620b}
}
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MLA
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Charkin, Dmitri O., et al. “Synthesis and cation distribution in the new bismuth oxyhalides with the Sillén-Aurivillius intergrowth structures.” Dalton Transactions, vol. 44, no. 47, Oct. 2015, pp. 20568-20576. https://doi.org/10.1039/c5dt02620b.