New insights into polymer mediated formation of anatase mesocrystals
Тип публикации: Journal Article
Дата публикации: 2017-05-23
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SJR: 0.520
CiteScore: 5.2
Impact factor: 2.6
ISSN: 14668033
General Chemistry
Condensed Matter Physics
General Materials Science
Краткое описание
The reaction between (NH4)2TiF6 and H3BO3 in the presence of varying quantities of PEG-6000 was used to form NH4TiOF3 mesocrystals (MCs). The amount of PEG-6000, employed as a template, is crucial to the formation of defect free, non-agglomerated NH4TiOF3 MCs; high concentrations lead to MC agglomeration, lower ones result in centralized defects. This polymer-mediated formation process may be understood using an analogy with known polymerization reactions. The oxofluorotitanate MCs readily undergo a thermal topotactic transformation to give anatase MCs with photocatalytic activity. The TiO2 MCs are porous, with highly orientated lamellar crystallites that form part of the larger mesocrystal structure.
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Boytsova O. et al. New insights into polymer mediated formation of anatase mesocrystals // CrystEngComm. 2017. Vol. 19. No. 24. pp. 3281-3287.
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Boytsova O., Sadovnikov A. A., Yorov Kh. E., Beltiukov A. N., Baranchikov A. E., Ivanov V. V., Zhong X., Lewis D. J., O'Brien P., SUTHERLAND A. New insights into polymer mediated formation of anatase mesocrystals // CrystEngComm. 2017. Vol. 19. No. 24. pp. 3281-3287.
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TY - JOUR
DO - 10.1039/c6ce01985d
UR - https://xlink.rsc.org/?DOI=C6CE01985D
TI - New insights into polymer mediated formation of anatase mesocrystals
T2 - CrystEngComm
AU - Boytsova, Olga
AU - Sadovnikov, A. A.
AU - Yorov, Kh E
AU - Beltiukov, Artemii N
AU - Baranchikov, Alexander E
AU - Ivanov, V. V.
AU - Zhong, Xiangli
AU - Lewis, David J.
AU - O'Brien, P.
AU - SUTHERLAND, A
PY - 2017
DA - 2017/05/23
PB - Royal Society of Chemistry (RSC)
SP - 3281-3287
IS - 24
VL - 19
SN - 1466-8033
ER -
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@article{2017_Boytsova,
author = {Olga Boytsova and A. A. Sadovnikov and Kh E Yorov and Artemii N Beltiukov and Alexander E Baranchikov and V. V. Ivanov and Xiangli Zhong and David J. Lewis and P. O'Brien and A SUTHERLAND},
title = {New insights into polymer mediated formation of anatase mesocrystals},
journal = {CrystEngComm},
year = {2017},
volume = {19},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=C6CE01985D},
number = {24},
pages = {3281--3287},
doi = {10.1039/c6ce01985d}
}
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MLA
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Boytsova, Olga, et al. “New insights into polymer mediated formation of anatase mesocrystals.” CrystEngComm, vol. 19, no. 24, May. 2017, pp. 3281-3287. https://xlink.rsc.org/?DOI=C6CE01985D.