CrystEngComm

, volume 19 , issue 24 , pages 3281-3287

New insights into polymer mediated formation of anatase mesocrystals

Olga Boytsova ^{1, 2, 3}

A. A. Sadovnikov ²

Kh E Yorov ³

Artemii N Beltiukov ⁴

Alexander E Baranchikov ²

V. V. Ivanov ^{2, 5}

Xiangli Zhong ⁶

David J. Lewis ⁶

P. O'Brien ^{6, 7}

A SUTHERLAND ¹

Hide authors affiliations Show authors affiliations: 7 affiliations

Aston Institute of Materials Research, Aston University, Birmingham, UK |

Kurnakov Institute of General and Inorganic Chemistry of RAS, Leninskii Ave. 31, Moscow, Russia |

Lomonosov Moscow State University, Leninskie Gory, 1, Moscow, Russia |

⁴

Physical-Technical Institute of UB RAS, Kirova str. 132, Izhevsk, 426000 Russia |

⁵

Tomsk State University, Lenina av.36, Tomsk, Russia |

⁶

School of Materials, University of Manchester, Oxford Road, Manchester, UK |

⁷

School of Chemistry, University of Manchester, Oxford road, Manchester, UK |

Publication type: Journal Article

Publication date: 2017-05-23

Royal Society of Chemistry (RSC)

CrystEngComm

scimago Q2

wos Q2

SJR: 0.520

CiteScore: 5.2

Impact factor: 2.6

ISSN: 14668033

DOI: 10.1039/c6ce01985d

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General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

The reaction between (NH4)2TiF6 and H3BO3 in the presence of varying quantities of PEG-6000 was used to form NH4TiOF3 mesocrystals (MCs). The amount of PEG-6000, employed as a template, is crucial to the formation of defect free, non-agglomerated NH4TiOF3 MCs; high concentrations lead to MC agglomeration, lower ones result in centralized defects. This polymer-mediated formation process may be understood using an analogy with known polymerization reactions. The oxofluorotitanate MCs readily undergo a thermal topotactic transformation to give anatase MCs with photocatalytic activity. The TiO2 MCs are porous, with highly orientated lamellar crystallites that form part of the larger mesocrystal structure.

Found

2 citations

Ivanov Vladimir

🥼

DSc in Chemistry, full member of the Russian Academy of Sciences

513 publications, 6 825 citations, 137 reviews

h-index: 37

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Lomonosov Moscow State University

National Research University Higher School of Economics

Solid state chemistry

1 citation

Baranchikov Alexander

PhD in Chemistry

401 publications, 5 272 citations, 274 reviews

h-index: 32

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Hydrothermal synthesis

Inorganic Chemistry

Low-temperature nitrogen adsorption

Rare-earth elements

Scanning electron microscopy

X-ray diffraction (XRD)

1 citation

Yapryntsev Alexey

🥼 🤝

PhD in Chemistry

83 publications, 733 citations

h-index: 17

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

1 citation

Naranov Evgeny

🥼 🤝

PhD in Chemistry

53 publications, 674 citations, 14 reviews

h-index: 14

Lomonosov Moscow State University

A.V. Topchiev Institute of Petrochemical Synthesis RAS

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Boytsova O. et al. New insights into polymer mediated formation of anatase mesocrystals // CrystEngComm. 2017. Vol. 19. No. 24. pp. 3281-3287.

GOST all authors (up to 50) Copy

Boytsova O., Sadovnikov A. A., Yorov Kh. E., Beltiukov A. N., Baranchikov A. E., Ivanov V. V., Zhong X., Lewis D. J., O'Brien P., SUTHERLAND A. New insights into polymer mediated formation of anatase mesocrystals // CrystEngComm. 2017. Vol. 19. No. 24. pp. 3281-3287.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/c6ce01985d

UR - https://xlink.rsc.org/?DOI=C6CE01985D

TI - New insights into polymer mediated formation of anatase mesocrystals

T2 - CrystEngComm

AU - Boytsova, Olga

AU - Sadovnikov, A. A.

AU - Yorov, Kh E

AU - Beltiukov, Artemii N

AU - Baranchikov, Alexander E

AU - Ivanov, V. V.

AU - Zhong, Xiangli

AU - Lewis, David J.

AU - O'Brien, P.

AU - SUTHERLAND, A

PY - 2017

DA - 2017/05/23

PB - Royal Society of Chemistry (RSC)

SP - 3281-3287

IS - 24

VL - 19

SN - 1466-8033

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2017_Boytsova,

author = {Olga Boytsova and A. A. Sadovnikov and Kh E Yorov and Artemii N Beltiukov and Alexander E Baranchikov and V. V. Ivanov and Xiangli Zhong and David J. Lewis and P. O'Brien and A SUTHERLAND},

title = {New insights into polymer mediated formation of anatase mesocrystals},

journal = {CrystEngComm},

year = {2017},

volume = {19},

publisher = {Royal Society of Chemistry (RSC)},

month = {may},

url = {https://xlink.rsc.org/?DOI=C6CE01985D},

number = {24},

pages = {3281--3287},

doi = {10.1039/c6ce01985d}

}

MLA

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MLA Copy

Boytsova, Olga, et al. “New insights into polymer mediated formation of anatase mesocrystals.” CrystEngComm, vol. 19, no. 24, May. 2017, pp. 3281-3287. https://xlink.rsc.org/?DOI=C6CE01985D.

Publisher

Royal Society of Chemistry (RSC)

Journal

CrystEngComm

scimago Q2

wos Q2

SJR

0.520

CiteScore

5.2

Impact factor

2.6

ISSN

14668033 (Print, Electronic)

Labs

Laboratory of synthesis of functional materials and processing of mineral raw materials

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