New insights into the breathing phenomenon in ZIF-4
J Gandara Loe
1
,
Jesus Gandara-Loe
2, 3, 4, 5, 6
,
Alexander Missyul
6, 7, 8, 9
,
François Fauth
6, 7, 8, 9
,
Zhe Wang
10
,
Luke L Daemen
11, 12, 13, 14
,
Yongqiang Cheng
10, 11, 12, 13, 14
,
Anibal J. Ramirez Cuesta
10, 11, 12, 13, 14
,
Peter I. Ravikovitch
14, 15, 16, 17
,
J Silvestre-Albero
1, 2, 3, 4, 5, 6
2
Laboratorio de Materiales Avanzados
3
Departamento de Química Inorgánica-IUMA
5
E-03690 San Vicente Del Raspeig
6
SPAIN
|
9
E-08290 Cerdanyola Del Vallés
|
12
Spallation Neutron Source
13
Oak Ridge
|
14
Usa
|
15
ExxonMobil Research and Engineering Co., Annandale, New Jersey, USA
|
16
ExxonMobil Research and Engineering Co.
17
Annandale
|
Publication type: Journal Article
Publication date: 2019-05-16
scimago Q1
wos Q1
SJR: 2.462
CiteScore: 16.7
Impact factor: 9.5
ISSN: 20507488, 20507496, 09599428, 13645501
General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract
Structural changes in ZIFs upon adsorption remain a paradigm due to the sensitivity of the adsorption mechanism to the nature of the organic ligands and gas probe molecules. Synchrotron X-ray diffraction under operando conditions clearly demonstrates for the first time that ZIF-4 exhibits a structural reorientation from a narrow-pore (np) to a new expanded-pore (ep) structure upon N2 adsorption, while it does not do so for CO2 adsorption. The existence of an expanded-pore structure of ZIF-4 has also been predicted by molecular simulations. In simulations the expanded structure was stabilized by entropy at high temperatures and by strong adsorption of N2 at low temperatures. These results are in perfect agreement with manometric adsorption measurements for N2 at 77 K that show the threshold pressure for breathing at ∼30 kPa. Inelastic neutron scattering (INS) measurements show that CO2 is also able to promote structural changes but, in this specific case, only at cryogenic temperatures (5 K).
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Total citations:
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Citations from 2024:
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(29%)
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Gandara Loe J. et al. New insights into the breathing phenomenon in ZIF-4 // Journal of Materials Chemistry A. 2019. Vol. 7. No. 24. pp. 14552-14558.
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Gandara Loe J., Gandara-Loe J., Missyul A., Fauth F., Wang Z., Daemen L. L., Cheng Y., Cuesta A. J. R., Ravikovitch P. I., Silvestre-Albero J. New insights into the breathing phenomenon in ZIF-4 // Journal of Materials Chemistry A. 2019. Vol. 7. No. 24. pp. 14552-14558.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c8ta09713e
UR - https://xlink.rsc.org/?DOI=C8TA09713E
TI - New insights into the breathing phenomenon in ZIF-4
T2 - Journal of Materials Chemistry A
AU - Gandara Loe, J
AU - Gandara-Loe, Jesus
AU - Missyul, Alexander
AU - Fauth, François
AU - Wang, Zhe
AU - Daemen, Luke L
AU - Cheng, Yongqiang
AU - Cuesta, Anibal J. Ramirez
AU - Ravikovitch, Peter I.
AU - Silvestre-Albero, J
PY - 2019
DA - 2019/05/16
PB - Royal Society of Chemistry (RSC)
SP - 14552-14558
IS - 24
VL - 7
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
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BibTex (up to 50 authors)
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@article{2019_Gandara Loe,
author = {J Gandara Loe and Jesus Gandara-Loe and Alexander Missyul and François Fauth and Zhe Wang and Luke L Daemen and Yongqiang Cheng and Anibal J. Ramirez Cuesta and Peter I. Ravikovitch and J Silvestre-Albero},
title = {New insights into the breathing phenomenon in ZIF-4},
journal = {Journal of Materials Chemistry A},
year = {2019},
volume = {7},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=C8TA09713E},
number = {24},
pages = {14552--14558},
doi = {10.1039/c8ta09713e}
}
Cite this
MLA
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Gandara Loe, J., et al. “New insights into the breathing phenomenon in ZIF-4.” Journal of Materials Chemistry A, vol. 7, no. 24, May. 2019, pp. 14552-14558. https://xlink.rsc.org/?DOI=C8TA09713E.