Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation
Тип публикации: Journal Article
Дата публикации: 2020-01-15
scimago Q1
wos Q2
БС1
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
31970378
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Краткое описание
Deprotonation of fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3Br] (R = H, Me, Ph) produces the corresponding diphosphinomethanide derivatives fac-[(κ3P,C,P-Ph2PC(R)PPh2)Mn(CO)3], which are prone to activate H2 to form the hydride complexes fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3H]. The substitution of the dppm bridge improves dramatically the reaction efficiency and this was rationalized by DFT calculations.
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Kireev N. V. et al. Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation // Chemical Communications. 2020. Vol. 56. No. 14. pp. 2139-2142.
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Kireev N. V. et al. Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation // Chemical Communications. 2020. Vol. 56. No. 14. pp. 2139-2142.
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TY - JOUR
DO - 10.1039/c9cc07713h
UR - https://xlink.rsc.org/?DOI=C9CC07713H
TI - Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation
T2 - Chemical Communications
AU - Kireev, Nikolay V
AU - Filippov, Oleg A.
AU - Gulyaeva, Ekaterina S
AU - Shubina, Elena S.
AU - Vendier, Laure
AU - Canac, Yves
AU - Sortais, Jean-Baptiste
AU - Lugan, Noël
AU - Valyaev, D. A.
PY - 2020
DA - 2020/01/15
PB - Royal Society of Chemistry (RSC)
SP - 2139-2142
IS - 14
VL - 56
PMID - 31970378
SN - 1359-7345
SN - 1364-548X
ER -
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@article{2020_Kireev,
author = {Nikolay V Kireev and Oleg A. Filippov and Ekaterina S Gulyaeva and Elena S. Shubina and Laure Vendier and Yves Canac and Jean-Baptiste Sortais and Noël Lugan and D. A. Valyaev and others},
title = {Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation},
journal = {Chemical Communications},
year = {2020},
volume = {56},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=C9CC07713H},
number = {14},
pages = {2139--2142},
doi = {10.1039/c9cc07713h}
}
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MLA
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Kireev, Nikolay V., et al. “Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation.” Chemical Communications, vol. 56, no. 14, Jan. 2020, pp. 2139-2142. https://xlink.rsc.org/?DOI=C9CC07713H.
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