volume 56 issue 14 pages 2139-2142

Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation

Nikolay V Kireev 1, 2, 3, 4, 5, 6, 7
Oleg A. Filippov 1, 3, 4, 5, 6
Ekaterina S Gulyaeva 1, 3, 4, 5, 6
Elena S. Shubina 1, 3, 4, 5, 6, 8, 9
Laure Vendier 10, 11, 12, 13, 14, 15
Yves Canac 10, 11, 12, 13, 14, 15
Jean-Baptiste Sortais 10, 11, 12, 13, 14, 15, 16
Noël Lugan 10, 11, 12, 13, 14, 15
D. A. Valyaev 10, 11, 12, 13, 14, 15
Publication typeJournal Article
Publication date2020-01-15
scimago Q1
wos Q2
SJR1.037
CiteScore7.4
Impact factor4.2
ISSN13597345, 1364548X
PubMed ID:  31970378
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Deprotonation of fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3Br] (R = H, Me, Ph) produces the corresponding diphosphinomethanide derivatives fac-[(κ3P,C,P-Ph2PC(R)PPh2)Mn(CO)3], which are prone to activate H2 to form the hydride complexes fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3H]. The substitution of the dppm bridge improves dramatically the reaction efficiency and this was rationalized by DFT calculations.
Found 
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Kireev N. V. et al. Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation // Chemical Communications. 2020. Vol. 56. No. 14. pp. 2139-2142.
GOST all authors (up to 50) Copy
Kireev N. V. et al. Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation // Chemical Communications. 2020. Vol. 56. No. 14. pp. 2139-2142.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c9cc07713h
UR - https://xlink.rsc.org/?DOI=C9CC07713H
TI - Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation
T2 - Chemical Communications
AU - Kireev, Nikolay V
AU - Filippov, Oleg A.
AU - Gulyaeva, Ekaterina S
AU - Shubina, Elena S.
AU - Vendier, Laure
AU - Canac, Yves
AU - Sortais, Jean-Baptiste
AU - Lugan, Noël
AU - Valyaev, D. A.
PY - 2020
DA - 2020/01/15
PB - Royal Society of Chemistry (RSC)
SP - 2139-2142
IS - 14
VL - 56
PMID - 31970378
SN - 1359-7345
SN - 1364-548X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Kireev,
author = {Nikolay V Kireev and Oleg A. Filippov and Ekaterina S Gulyaeva and Elena S. Shubina and Laure Vendier and Yves Canac and Jean-Baptiste Sortais and Noël Lugan and D. A. Valyaev and others},
title = {Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation},
journal = {Chemical Communications},
year = {2020},
volume = {56},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=C9CC07713H},
number = {14},
pages = {2139--2142},
doi = {10.1039/c9cc07713h}
}
MLA
Cite this
MLA Copy
Kireev, Nikolay V., et al. “Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation.” Chemical Communications, vol. 56, no. 14, Jan. 2020, pp. 2139-2142. https://xlink.rsc.org/?DOI=C9CC07713H.