Chemical Communications

, том 56 , издание 14 , страницы 2139-2142

Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation

Тип публикации: Journal Article

Дата публикации: 2020-01-15

Royal Society of Chemistry (RSC)

Chemical Communications

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SJR: 0.907

CiteScore: 7.2

Impact factor: 4.3

ISSN: 13597345, 1364548X

DOI: 10.1039/c9cc07713h

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PubMed ID: 31970378

Materials Chemistry

Metals and Alloys

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Deprotonation of fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3Br] (R = H, Me, Ph) produces the corresponding diphosphinomethanide derivatives fac-[(κ3P,C,P-Ph2PC(R)PPh2)Mn(CO)3], which are prone to activate H2 to form the hydride complexes fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3H]. The substitution of the dppm bridge improves dramatically the reaction efficiency and this was rationalized by DFT calculations.

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Kireev N. V. et al. Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation // Chemical Communications. 2020. Vol. 56. No. 14. pp. 2139-2142.

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TY - JOUR

DO - 10.1039/c9cc07713h

UR - https://xlink.rsc.org/?DOI=C9CC07713H

TI - Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation

T2 - Chemical Communications

AU - Kireev, Nikolay V

AU - Filippov, Oleg A.

AU - Gulyaeva, Ekaterina S

AU - Shubina, Elena S.

AU - Vendier, Laure

AU - Canac, Yves

AU - Sortais, Jean-Baptiste

AU - Lugan, Noël

AU - Valyaev, D. A.

PY - 2020

DA - 2020/01/15

PB - Royal Society of Chemistry (RSC)

SP - 2139-2142

IS - 14

VL - 56

PMID - 31970378

SN - 1359-7345

SN - 1364-548X

ER -

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@article{2020_Kireev,

author = {Nikolay V Kireev and Oleg A. Filippov and Ekaterina S Gulyaeva and Elena S. Shubina and Laure Vendier and Yves Canac and Jean-Baptiste Sortais and Noël Lugan and D. A. Valyaev and others},

title = {Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation},

journal = {Chemical Communications},

year = {2020},

volume = {56},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://xlink.rsc.org/?DOI=C9CC07713H},

number = {14},

pages = {2139--2142},

doi = {10.1039/c9cc07713h}

}

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Kireev, Nikolay V., et al. “Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation.” Chemical Communications, vol. 56, no. 14, Jan. 2020, pp. 2139-2142. https://xlink.rsc.org/?DOI=C9CC07713H.

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Royal Society of Chemistry (RSC)

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Chemical Communications

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