Open Access

Dalton Transactions

, volume 48 , issue 28 , pages 10526-10536

Structural and magnetic characterization of Ni(ii), Co(ii), and Fe(ii) binuclear complexes on a bis(pyridyl-triazolyl)alkane basis

Alexey A. Gusev ¹

Alexey Gusev ^{2, 3, 4}

Ivan Nemec ^{5, 6, 7, 8, 9, 10, 11}

Radovan Herchel ^{5, 7, 8, 9, 10, 11}

Irina Riush ^{1, 2, 3, 4}

Ján Titiš ^{12, 13, 14, 15, 16, 17}

R. Bo a ^{12, 13, 14, 15, 16, 17}

Konstantin A. Lyssenko ¹⁸

Konstantin Lyssenko ^{4, 19, 20, 21}

Mikhail A. Kiskin ²²

Mikhail Kiskin ^{4, 20, 23, 24}

Igor L. Eremenko ^{4, 18, 19, 20, 21, 22, 23}

Wolfgang Linert ^{25, 26, 27, 28, 29}

Wolfgang Linert ²⁵

Hide authors affiliations Show authors affiliations: 29 affiliations

Crimean Federal University, Simferopol, Crimea, Russian Federation |

Crimean Federal University |

Simferopol |

⁴

RUSSIAN FEDERATION |

⁵

Department of Inorganic Chemistry, Faculty of Science, Palacký University, 77147 Olomouc, Czech Republic |

⁶

Central European Institute of Technology, CEITEC BUT, Technická 3058/10, Brno, Czech Republic |

⁷

Department of Inorganic Chemistry

⁸

Faculty of science

⁹

Palacký University |

¹⁰

77147 Olomouc |

¹¹

Czech Republic |

¹²

Department of Chemistry, FPV, University of SS Cyril and Methodius, 91701 Trnava, Slovakia |

¹³

DEPARTMENT OF CHEMISTRY

¹⁴

FPV

¹⁵

University of SS Cyril and Methodius |

¹⁶

91701 Trnava |

¹⁷

Slovakia |

¹⁸

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation |

¹⁹

A. N. Nesmeyanov Institute of Organoelement Compounds |

²⁰

RUSSIAN ACADEMY OF SCIENCES

²¹

119991 Moscow

²²

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation |

²³

N.S. Kurnakov Institute of General and Inorganic Chemistry |

²⁴

Moscow

²⁵

Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-AC, A-1060 Vienna, Austria |

²⁶

Institute of Applied Synthetic Chemistry

²⁷

VIENNA University of Technology |

²⁸

A-1060 Vienna

²⁹

Austria |

Publication type: Journal Article

Publication date: 2019-06-24

Royal Society of Chemistry (RSC)

Dalton Transactions

scimago Q2

wos Q1

SJR: 0.653

CiteScore: 6.0

Impact factor: 3.3

ISSN: 14779226, 14779234

DOI: 10.1039/c9dt01391a

Copy DOI

PubMed ID: 31231741

Inorganic Chemistry

Abstract

Reactions of bis[5-(2-pyridyl)-1,2,4-triazol-3-yl]alkanes (alkane spacers = –CH2– in L2, –C3H6– in L3, –C4H8– in L4) with M(II)A2 salts (M = Ni, Co, Fe) resulted in the preparation of five series of mononuclear ([M(L2)(H2O)2]2+, 1a–c) or binuclear ([M2(L3)2(H2O)4]4+, 2a–c; ([M2(L4)2(H2O)4]4+, 3a–c, [M2(L3)2(μ-ox)]2+, 4a–c; [M2(L4)2(μ-ox)]2+, 5a–c) complexes. The crystal structures of ten complexes were determined by single-crystal X-ray crystallography. Magnetic properties of the compounds were characterized by SQUID magnetometry and were analyzed by fitting on a spin Hamiltonian model. It was revealed that Fe(II) and Co(II) compounds exhibit non-negligible anisotropy and in the case of 2a–c and 3a–c complexes weak ferromagnetic interactions between the metal centers were observed. In the case of complexes containing an {M2(μ-ox)}2+ core strong antiferromagnetic interactions were observed within the dimer. Remarkably, solid state luminescence of Co(II) and Fe(II) complexes (1b, 2b, 3b and 1c, 2c, 3c) was observed.

Found

2 citations

Kiskin Mikhail

🥼 🤝

DSc in Chemistry, professor

407 publications, 5 037 citations

h-index: 31

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Magnets

Nanoparticles

1 citation

Pavlov Alexander

🥼 🤝

DSc in Chemistry

120 publications, 1 961 citations

h-index: 23

Bauman Moscow State Technical University

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Mendeleev University of Chemical Technology of Russia

Research interests

Digital Chemistry

Digital Materials Science

Molecular magnetism

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Gusev A. A. et al. Structural and magnetic characterization of Ni(ii), Co(ii), and Fe(ii) binuclear complexes on a bis(pyridyl-triazolyl)alkane basis // Dalton Transactions. 2019. Vol. 48. No. 28. pp. 10526-10536.

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RIS Copy

TY - JOUR

DO - 10.1039/c9dt01391a

UR - https://xlink.rsc.org/?DOI=C9DT01391A

TI - Structural and magnetic characterization of Ni(ii), Co(ii), and Fe(ii) binuclear complexes on a bis(pyridyl-triazolyl)alkane basis

T2 - Dalton Transactions

AU - Gusev, Alexey A.

AU - Gusev, Alexey

AU - Nemec, Ivan

AU - Herchel, Radovan

AU - Riush, Irina

AU - Titiš, Ján

AU - Bo a, R.

AU - Lyssenko, Konstantin A.

AU - Lyssenko, Konstantin

AU - Kiskin, Mikhail A.

AU - Kiskin, Mikhail

AU - Eremenko, Igor L.

AU - Linert, Wolfgang

PY - 2019

DA - 2019/06/24

PB - Royal Society of Chemistry (RSC)

SP - 10526-10536

IS - 28

VL - 48

PMID - 31231741

SN - 1477-9226

SN - 1477-9234

ER -

BibTex |

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@article{2019_Gusev,

author = {Alexey A. Gusev and Alexey Gusev and Ivan Nemec and Radovan Herchel and Irina Riush and Ján Titiš and R. Bo a and Konstantin A. Lyssenko and Konstantin Lyssenko and Mikhail A. Kiskin and Mikhail Kiskin and Igor L. Eremenko and Wolfgang Linert and Wolfgang Linert and others},

title = {Structural and magnetic characterization of Ni(ii), Co(ii), and Fe(ii) binuclear complexes on a bis(pyridyl-triazolyl)alkane basis},

journal = {Dalton Transactions},

year = {2019},

volume = {48},

publisher = {Royal Society of Chemistry (RSC)},

month = {jun},

url = {https://xlink.rsc.org/?DOI=C9DT01391A},

number = {28},

pages = {10526--10536},

doi = {10.1039/c9dt01391a}

}

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Gusev, Alexey A., et al. “Structural and magnetic characterization of Ni(ii), Co(ii), and Fe(ii) binuclear complexes on a bis(pyridyl-triazolyl)alkane basis.” Dalton Transactions, vol. 48, no. 28, Jun. 2019, pp. 10526-10536. https://xlink.rsc.org/?DOI=C9DT01391A.

Publisher

Royal Society of Chemistry (RSC)

Journal

Dalton Transactions

scimago Q2

wos Q1

SJR

0.653

CiteScore

6.0

Impact factor

3.3

ISSN

14779226 (Print)

14779234 (Electronic)

Labs

Laboratory of Chemistry of Coordinating Polynuclear Compounds

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