C–F activation reactions at germylium ions: dehydrofluorination of fluoralkanes
M Talavera
1, 2, 3, 4, 5
,
Gisa Meißner
1, 2, 3, 4, 5
,
Simon G Rachor
1, 2, 3, 4, 5
,
Thomas Braun
1, 2, 3, 4, 5
1
2
DEPARTMENT OF CHEMISTRY
4
12489 Berlin
5
GERMANY
|
Publication type: Journal Article
Publication date: 2020-03-20
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
32196045
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Reactions of the trityl cations with germanes afford the germylium ions [R3Ge][B(C6F5)4] (1a: R = Et, 1b: R = Ph, 1c: R = nBu). These compounds react with germane or fluorogermane to give polynuclear species, which are sources of the mononuclear ions, The latter convert with phosphines to yield the [R3Ge-PR3]+ (4a: R = Et, 4b: R = Ph) cations. Catalytic dehydrofluorination reactions were observed for the C–F bond activation of fluoroalkanes when using germanes as hydrogen source.
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Total citations:
22
Citations from 2025:
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(4.55%)
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GOST
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Talavera M. et al. C–F activation reactions at germylium ions: dehydrofluorination of fluoralkanes // Chemical Communications. 2020. Vol. 56. No. 32. pp. 4452-4455.
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Talavera M., Meißner G., Rachor S. G., Braun T. C–F activation reactions at germylium ions: dehydrofluorination of fluoralkanes // Chemical Communications. 2020. Vol. 56. No. 32. pp. 4452-4455.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d0cc01420f
UR - https://xlink.rsc.org/?DOI=D0CC01420F
TI - C–F activation reactions at germylium ions: dehydrofluorination of fluoralkanes
T2 - Chemical Communications
AU - Talavera, M
AU - Meißner, Gisa
AU - Rachor, Simon G
AU - Braun, Thomas
PY - 2020
DA - 2020/03/20
PB - Royal Society of Chemistry (RSC)
SP - 4452-4455
IS - 32
VL - 56
PMID - 32196045
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Talavera,
author = {M Talavera and Gisa Meißner and Simon G Rachor and Thomas Braun},
title = {C–F activation reactions at germylium ions: dehydrofluorination of fluoralkanes},
journal = {Chemical Communications},
year = {2020},
volume = {56},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://xlink.rsc.org/?DOI=D0CC01420F},
number = {32},
pages = {4452--4455},
doi = {10.1039/d0cc01420f}
}
Cite this
MLA
Copy
Talavera, M., et al. “C–F activation reactions at germylium ions: dehydrofluorination of fluoralkanes.” Chemical Communications, vol. 56, no. 32, Mar. 2020, pp. 4452-4455. https://xlink.rsc.org/?DOI=D0CC01420F.