Royal Society of Chemistry (RSC)
Organic and Biomolecular Chemistry
,  volume 19 ,  issue 3 ,  pages 548-551

Pd/C-Catalyzed transfer hydrogenation of N–H indoles with trifluoroethanol and tetrahydroxydiboron as the hydrogen source

Xiao Yu Zhou 1, 2, 3, 4, 5
, 
Xia Chen 1
1
 
2
 
School of Chemistry and Materials Engineering
3
 
4
 
Liupanshui | 
5
 
CHINA | 
Publication type: Journal Article
Publication date: 2021-01-01
Royal Society of Chemistry (RSC)
scimago Q2
wos Q2
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
DOI:  10.1039/d0ob02080j
PubMed ID:  33367398
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Under the guidance of the known mechanism of the hydrogenation of indoles and transfer hydrogenation with tetrahydroxydiboron (B2(OH)4), Pd/C catalyzed transfer hydrogenation of N–H indoles with trifluoroethanol and tetrahydroxydiborane as the hydrogen source has been developed. This provides an efficient strategy and catalytic system for the reduction of un-activated N–H indoles, and N–H indolines are obtained with good to excellent yields. In addition, a series of the isotopic labelling experiments were carried out to probe the mechanism.
Found 
Found 

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GOST |
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GOST Copy
Zhou X. Yu. et al. Pd/C-Catalyzed transfer hydrogenation of N–H indoles with trifluoroethanol and tetrahydroxydiboron as the hydrogen source // Organic and Biomolecular Chemistry. 2021. Vol. 19. No. 3. pp. 548-551.
GOST all authors (up to 50) Copy
Zhou X. Yu., Chen X. Pd/C-Catalyzed transfer hydrogenation of N–H indoles with trifluoroethanol and tetrahydroxydiboron as the hydrogen source // Organic and Biomolecular Chemistry. 2021. Vol. 19. No. 3. pp. 548-551.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/d0ob02080j
UR - https://xlink.rsc.org/?DOI=D0OB02080J
TI - Pd/C-Catalyzed transfer hydrogenation of N–H indoles with trifluoroethanol and tetrahydroxydiboron as the hydrogen source
T2 - Organic and Biomolecular Chemistry
AU - Zhou, Xiao Yu
AU - Chen, Xia
PY - 2021
DA - 2021/01/01
PB - Royal Society of Chemistry (RSC)
SP - 548-551
IS - 3
VL - 19
PMID - 33367398
SN - 1477-0520
SN - 1477-0539
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Zhou,
author = {Xiao Yu Zhou and Xia Chen},
title = {Pd/C-Catalyzed transfer hydrogenation of N–H indoles with trifluoroethanol and tetrahydroxydiboron as the hydrogen source},
journal = {Organic and Biomolecular Chemistry},
year = {2021},
volume = {19},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=D0OB02080J},
number = {3},
pages = {548--551},
doi = {10.1039/d0ob02080j}
}
MLA
Cite this
MLA Copy
Zhou, Xiao Yu., et al. “Pd/C-Catalyzed transfer hydrogenation of N–H indoles with trifluoroethanol and tetrahydroxydiboron as the hydrogen source.” Organic and Biomolecular Chemistry, vol. 19, no. 3, Jan. 2021, pp. 548-551. https://xlink.rsc.org/?DOI=D0OB02080J.