Chemical Communications, volume 58, issue 21, pages 3509-3512
In situ silane activation enables catalytic reduction of carboxylic acids
3
GlaxoSmithKline, Gunnels Wood Road, Stevenage, SG1 2NY, UK
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4
GlaxoSmithKline, Gunnels Wood Road, Stevenage, UK
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Publication type: Journal Article
Publication date: 2022-01-20
Journal:
Chemical Communications
Quartile SCImago
Q1
Quartile WOS
Q2
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
We describe a catalytic system for the conversion of carboxylic acids into alcohols using substoichiometric zinc acetate and N-methyl morpholine, in combination with phenylsilane as the nominal terminal reductant. Reaction monitoring by 19F NMR spectroscopy demonstrates that the reaction proceeds by mutual activation of the carboxylic acid and silane through the in situ generation of silyl ester intermediates.
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Stoll E. L. et al. In situ silane activation enables catalytic reduction of carboxylic acids // Chemical Communications. 2022. Vol. 58. No. 21. pp. 3509-3512.
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Stoll E. L., Barber T., Hirst D. J., Denton R. M. In situ silane activation enables catalytic reduction of carboxylic acids // Chemical Communications. 2022. Vol. 58. No. 21. pp. 3509-3512.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d1cc03396d
UR - https://doi.org/10.1039/d1cc03396d
TI - In situ silane activation enables catalytic reduction of carboxylic acids
T2 - Chemical Communications
AU - Stoll, Emma L
AU - Barber, Thomas
AU - Hirst, David J.
AU - Denton, Ross M.
PY - 2022
DA - 2022/01/20
PB - Royal Society of Chemistry (RSC)
SP - 3509-3512
IS - 21
VL - 58
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex
Copy
@article{2022_Stoll,
author = {Emma L Stoll and Thomas Barber and David J. Hirst and Ross M. Denton},
title = {In situ silane activation enables catalytic reduction of carboxylic acids},
journal = {Chemical Communications},
year = {2022},
volume = {58},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/d1cc03396d},
number = {21},
pages = {3509--3512},
doi = {10.1039/d1cc03396d}
}
Cite this
MLA
Copy
Stoll, Emma L., et al. “In situ silane activation enables catalytic reduction of carboxylic acids.” Chemical Communications, vol. 58, no. 21, Jan. 2022, pp. 3509-3512. https://doi.org/10.1039/d1cc03396d.