Physical Chemistry Chemical Physics, том 23, издание 31, номера страниц: 16690-16697

Optimization of the photo-orientation rate of an azobenzene-containing polymer based on a kinetic model of photoinduced ordering

Тип документаJournal Article
Дата публикации2021
ИздательThe Royal Society of Chemistry
Название журналаPhysical Chemistry Chemical Physics
Квартиль по SCImagoQ1
Квартиль по Web of ScienceQ1
Импакт-фактор 20213.95
ISSN14639076, 14639084
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
The explicit dependence of the rate of photoinduced ordering (photo-orientation) of an azobenzene-containing liquid-crystalline polymer on the photostationary concentration of cis-azobenzene has been predicted theoretically and found experimentally. The employed kinetic model based on the photoinduced rearrangement of the domain structure of a liquid-crystalline material predicts the maximum rate of photo-orientation at ca. 50% content of the cis-isomer in the photostationary state of irradiation. For experimental fine tuning of the photostationary trans-cis ratio, the simultaneous irradiation of material with two beams of light with different wavelengths was employed. The excellent agreement of theory and experiment indicates that the difference of photostationary fractions of cis-azobenzene fragments in adjacent domains of different orientations is the driving force of photoinduced ordering.
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1. Bogdanov A. V., Bobrovsky A. Yu., Vorobiev A. Kh. Optimization of the photo-orientation rate of an azobenzene-containing polymer based on a kinetic model of photoinduced ordering // Physical Chemistry Chemical Physics. 2021. Т. 23. № 31. С. 16690–16697.


DO - 10.1039/d1cp01585k

UR -

TI - Optimization of the photo-orientation rate of an azobenzene-containing polymer based on a kinetic model of photoinduced ordering

T2 - Physical Chemistry Chemical Physics

AU - Bogdanov, Alexey V.

AU - Bobrovsky, Alexey Yu.

AU - Vorobiev, Andrey Kh.

PY - 2021

PB - Royal Society of Chemistry (RSC)

SP - 16690-16697

IS - 31

VL - 23

SN - 1463-9076

SN - 1463-9084

ER -

BibTex |


doi = {10.1039/d1cp01585k},

url = {},

year = 2021,

publisher = {Royal Society of Chemistry ({RSC})},

volume = {23},

number = {31},

pages = {16690--16697},

author = {Alexey V. Bogdanov and Alexey Yu. Bobrovsky and Andrey Kh. Vorobiev},

title = {Optimization of the photo-orientation rate of an azobenzene-containing polymer based on a kinetic model of photoinduced ordering},

journal = {Physical Chemistry Chemical Physics}


Bogdanov, Alexey V., et al. “Optimization of the Photo-Orientation Rate of an Azobenzene-Containing Polymer Based on a Kinetic Model of Photoinduced Ordering.” Physical Chemistry Chemical Physics, vol. 23, no. 31, 2021, pp. 16690–97. Crossref,