Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium, (ii) iridium and (iii) organic photoredox agents
Publication type: Journal Article
Publication date: 2021-07-26
scimago Q1
wos Q1
SJR: 11.467
CiteScore: 73.2
Impact factor: 39.0
ISSN: 03060012, 14604744
PubMed ID:
34309610
General Chemistry
Abstract
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier years, but such is the pace of progress that we will overlap very little with earlier comprehensive reviews. This review first presents an overview of the area of research and then examines recent examples of C–C, C–N, C–O and C–S bond formations via radical intermediates with transition metal and organic radical promoters. Recent successes with Birch reductions are also included. The transition metal chemistry will be restricted to photocatalysts based on the most widely used metals, Ru and Ir, but includes coupling chemistries that take advantage of low-valent nickel, or occasionally copper, complexes to process the radicals that are formed. Our focus is on developments in the past 10 years (2011–2021). This period has also seen great advances in the chemistry of organic photoredox reagents and the review covers this area. The review is intended to present highlights and is not comprehensive.
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Bell J. D. et al. Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium, (ii) iridium and (iii) organic photoredox agents // Chemical Society Reviews. 2021. Vol. 50. No. 17. pp. 9540-9685.
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Bell J. D., Murphy J. A. Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium, (ii) iridium and (iii) organic photoredox agents // Chemical Society Reviews. 2021. Vol. 50. No. 17. pp. 9540-9685.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d1cs00311a
UR - https://xlink.rsc.org/?DOI=D1CS00311A
TI - Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium, (ii) iridium and (iii) organic photoredox agents
T2 - Chemical Society Reviews
AU - Bell, Jonathan D
AU - Murphy, J A
PY - 2021
DA - 2021/07/26
PB - Royal Society of Chemistry (RSC)
SP - 9540-9685
IS - 17
VL - 50
PMID - 34309610
SN - 0306-0012
SN - 1460-4744
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Bell,
author = {Jonathan D Bell and J A Murphy},
title = {Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium, (ii) iridium and (iii) organic photoredox agents},
journal = {Chemical Society Reviews},
year = {2021},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://xlink.rsc.org/?DOI=D1CS00311A},
number = {17},
pages = {9540--9685},
doi = {10.1039/d1cs00311a}
}
Cite this
MLA
Copy
Bell, Jonathan D., et al. “Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium, (ii) iridium and (iii) organic photoredox agents.” Chemical Society Reviews, vol. 50, no. 17, Jul. 2021, pp. 9540-9685. https://xlink.rsc.org/?DOI=D1CS00311A.