Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines
Publication type: Journal Article
Publication date: 2021-09-06
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
34477191
Inorganic Chemistry
Abstract
Two luminescent Cu4I4-cubane tetramers with N-methyl-10-(p-halogenophenyl)-5,10-dihydrophenarsazine ligands were synthesized and characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction analysis. The UV–Vis absorption and emission properties were studied and rationalized by DFT and time-dependent DFT calculations. The luminescence behavior was found to be rather different from that of recently reported tetranuclear copper iodide cubane clusters based on As,O-analogues – 10-(aryl)phenoxarsines. The crystalline powders of both complexes exhibit the temperature-dependent dual-band emission: the low-energy emission originates from the cluster-centered (3CC) triplet state, whereas the high-energy emission was attributed to the intraligand (3IL) triplet state.
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Total citations:
19
Citations from 2025:
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(15.79%)
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GOST
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Galimova M. et al. Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines // Dalton Transactions. 2021. Vol. 50. No. 38. pp. 13421-13429.
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Galimova M., Zueva E. M., Dobrynin A., Kolesnikov I. E., Musin R. R., Musina E., Karasik A. A. Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines // Dalton Transactions. 2021. Vol. 50. No. 38. pp. 13421-13429.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d1dt02344f
UR - https://xlink.rsc.org/?DOI=D1DT02344F
TI - Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines
T2 - Dalton Transactions
AU - Galimova, Milyausha
AU - Zueva, Ekaterina M
AU - Dobrynin, Alexey
AU - Kolesnikov, Ilya E.
AU - Musin, Rustem R
AU - Musina, Elvira
AU - Karasik, Andrey A
PY - 2021
DA - 2021/09/06
PB - Royal Society of Chemistry (RSC)
SP - 13421-13429
IS - 38
VL - 50
PMID - 34477191
SN - 1477-9226
SN - 1477-9234
ER -
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BibTex (up to 50 authors)
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@article{2021_Galimova,
author = {Milyausha Galimova and Ekaterina M Zueva and Alexey Dobrynin and Ilya E. Kolesnikov and Rustem R Musin and Elvira Musina and Andrey A Karasik},
title = {Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines},
journal = {Dalton Transactions},
year = {2021},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://xlink.rsc.org/?DOI=D1DT02344F},
number = {38},
pages = {13421--13429},
doi = {10.1039/d1dt02344f}
}
Cite this
MLA
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Galimova, Milyausha, et al. “Luminescent Cu4I4-cubane clusters based on N-methyl-5,10-dihydrophenarsazines.” Dalton Transactions, vol. 50, no. 38, Sep. 2021, pp. 13421-13429. https://xlink.rsc.org/?DOI=D1DT02344F.