Selective dimerization of α-methylstyrene by tunable bis(catecholato)germane Lewis acid catalysts
Publication type: Journal Article
Publication date: 2021-10-19
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
34714312
Inorganic Chemistry
Abstract
The synthesis of a variety of bis(catecholato)germanes is reported. The Lewis acidity of the bis(catecholato)germanes was assessed using the experimental Gutmann-Beckett method and computational FIA and GEI methods. The oligomerization of alkenes using bis(catecholato)germanes demonstrates the use of these complexes in catalysis. The use of donor additives in the dimerization of α-methylstyrene resulted in selectivity control comparable to transition metal catalyst systems.
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Metrics
23
Total citations:
23
Citations from 2025:
6
(26.09%)
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MLA
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GOST
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Henry A. T. et al. Selective dimerization of α-methylstyrene by tunable bis(catecholato)germane Lewis acid catalysts // Dalton Transactions. 2021. Vol. 50. No. 43. pp. 15906-15913.
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Henry A. T., Cosby T. P. L., Boyle P. D., Baines K. M. Selective dimerization of α-methylstyrene by tunable bis(catecholato)germane Lewis acid catalysts // Dalton Transactions. 2021. Vol. 50. No. 43. pp. 15906-15913.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d1dt03180e
UR - https://xlink.rsc.org/?DOI=D1DT03180E
TI - Selective dimerization of α-methylstyrene by tunable bis(catecholato)germane Lewis acid catalysts
T2 - Dalton Transactions
AU - Henry, Andrew T.
AU - Cosby, Taylor P L
AU - Boyle, Paul D.
AU - Baines, Kim M.
PY - 2021
DA - 2021/10/19
PB - Royal Society of Chemistry (RSC)
SP - 15906-15913
IS - 43
VL - 50
PMID - 34714312
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Henry,
author = {Andrew T. Henry and Taylor P L Cosby and Paul D. Boyle and Kim M. Baines},
title = {Selective dimerization of α-methylstyrene by tunable bis(catecholato)germane Lewis acid catalysts},
journal = {Dalton Transactions},
year = {2021},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=D1DT03180E},
number = {43},
pages = {15906--15913},
doi = {10.1039/d1dt03180e}
}
Cite this
MLA
Copy
Henry, Andrew T., et al. “Selective dimerization of α-methylstyrene by tunable bis(catecholato)germane Lewis acid catalysts.” Dalton Transactions, vol. 50, no. 43, Oct. 2021, pp. 15906-15913. https://xlink.rsc.org/?DOI=D1DT03180E.