Open Access
Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
Alena N Kulakova
2, 3, 4, 5
,
Gautier Félix
1
,
Victor N. Khrustalev
3, 6
,
Elena S. Shubina
2, 4
,
Jérôme Long
1
,
J. P. Long
1
,
Yannick Guari
1
,
Saad Sene
1
,
Luís D. Carlos
7, 8
,
Alexey N Bilyachenko
2, 3, 4, 5
,
5
Publication type: Journal Article
Publication date: 2021-10-27
scimago Q1
wos Q2
SJR: 0.777
CiteScore: 7.6
Impact factor: 4.6
ISSN: 20462069
PubMed ID:
35494783
General Chemistry
General Chemical Engineering
Abstract
New luminescent cage-like tetranuclear silsesquioxanes [NEt4][(Ph4Si4O8)2(Tb3Eu)(NO3)4(OH)(EtOH)3(H2O)]·4(EtOH) (1) and [NEt4]2[(Ph4Si4O8)2(Tb2Eu2)(NO3)6(EtOH)2(MeCN)2]·4(MeCN) (2) present a tunable thermosensitive Tb3+-to-Eu3+ energy transfer driven by Tb3+ and Eu3+ emission and may be used as temperature sensors operating in the range 41-100 °C with excellent linearity (R2 = 0.9990) and repeatability (>95%). The thermometer performance was evidenced by the maximum relative sensitivity of 0.63% °C-1 achieved at 68 °C.
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26
Total citations:
26
Citations from 2024:
12
(46%)
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GOST
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Nigoghossian K. et al. Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission // RSC Advances. 2021. Vol. 11. No. 55. pp. 34735-34741.
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Nigoghossian K., Kulakova A. N., Félix G., Khrustalev V. N., Shubina E. S., Long J., Long J. P., Guari Y., Sene S., Carlos L. D., Bilyachenko A. N., Larionova J. Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission // RSC Advances. 2021. Vol. 11. No. 55. pp. 34735-34741.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/d1ra06755a
UR - https://xlink.rsc.org/?DOI=D1RA06755A
TI - Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
T2 - RSC Advances
AU - Nigoghossian, Karina
AU - Kulakova, Alena N
AU - Félix, Gautier
AU - Khrustalev, Victor N.
AU - Shubina, Elena S.
AU - Long, Jérôme
AU - Long, J. P.
AU - Guari, Yannick
AU - Sene, Saad
AU - Carlos, Luís D.
AU - Bilyachenko, Alexey N
AU - Larionova, Joulia
PY - 2021
DA - 2021/10/27
PB - Royal Society of Chemistry (RSC)
SP - 34735-34741
IS - 55
VL - 11
PMID - 35494783
SN - 2046-2069
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Nigoghossian,
author = {Karina Nigoghossian and Alena N Kulakova and Gautier Félix and Victor N. Khrustalev and Elena S. Shubina and Jérôme Long and J. P. Long and Yannick Guari and Saad Sene and Luís D. Carlos and Alexey N Bilyachenko and Joulia Larionova},
title = {Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission},
journal = {RSC Advances},
year = {2021},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=D1RA06755A},
number = {55},
pages = {34735--34741},
doi = {10.1039/d1ra06755a}
}
Cite this
MLA
Copy
Nigoghossian, Karina, et al. “Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission.” RSC Advances, vol. 11, no. 55, Oct. 2021, pp. 34735-34741. https://xlink.rsc.org/?DOI=D1RA06755A.