Royal Society of Chemistry (RSC)
Chemical Communications
,  volume 58 ,  issue 32 ,  pages 5017-5020

Fac-to-mer isomerization triggers hydride transfer from Mn(i) complex fac-[(dppm)Mn(CO)3H]

Elena S Osipova 1
, 
Elena Y. Osipova 2
, 
Ekaterina S Gulyaeva 1, 2, 3, 4
, 
Nikolay V Kireev 1, 2
, 
Sergey A Kovalenko 1, 2
, 
Christian Bijani 4
, 
Yves Canac 3, 4
, 
D. A. Valyaev 3, 4
, 
Oleg A. Filippov 1, 2
, 
Natalia V Belkova 1, 2
, 
Elena S. Shubina 1, 2
1
 
2
 
3
 
4
 
Publication type: Journal Article
Publication date: 2022-03-23
Royal Society of Chemistry (RSC)
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
DOI:  10.1039/d2cc00999d
PubMed ID:  35373227
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Low-temperature IR and NMR studies combined with DFT calculations revealed the mechanistic complexity of apparently simple reactions between Mn(I) complex fac-[(dppm)Mn(CO)3H] and Lewis acids (LA = Ph3C+, B(C6F5)3) involving the formation of so-far elusive meridional hydride species mer-[(dppm)Mn(CO)3H⋯LA] and unusual dearomatization of the Ph3C+ cation upon hydride transfer.
Found 
Found 
5 citations
Filippov Oleg
🥼
DSc in Chemistry
137 publications,  2 409 citations,  45 reviews
h-index: 26
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
4 citations
Shubina Elena
DSc in Chemistry, professor
264 publications,  5 882 citations,  16 reviews
h-index: 38
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Molecular spectroscopy
2 citations
Danshina Anastasia
🤝
26 publications,  98 citations
h-index: 6
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
Moscow Institute of Physics and Technology
Moscow Institute of Physics and Technology
1 citation
Afanasyev Oleg
51 publications,  1 268 citations,  11 reviews
h-index: 13
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
1 citation
Perekalin Dmitry
🥼
DSc in Chemistry
121 publications,  1 974 citations,  35 reviews
h-index: 25
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Asymmetric metal complex catalysis
Catalysis
Organometallic Chemistry
Photochemistry
1 citation
Gafurov Zufar
🤝
PhD in Chemistry
48 publications,  641 citations
h-index: 17
Kazan Federal University
Kazan Federal University
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
Research interests
Catalysis
Coordination Chemistry
Electrochemistry
Organometallic Chemistry
1 citation
Pavlov Alexander
🥼 🤝
DSc in Chemistry
120 publications,  1 969 citations
h-index: 23
Bauman Moscow State Technical University
Bauman Moscow State Technical University
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Mendeleev University of Chemical Technology of Russia
Mendeleev University of Chemical Technology of Russia
Research interests
Digital Chemistry
Digital Materials Science
Molecular magnetism
1 citation
Sakhapov Ilyas
🥼 🤝
PhD in Chemistry
44 publications,  355 citations
h-index: 12
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
Research interests
Electrochemistry
Green chemistry
1 citation
Chusov Denis
DSc in Chemistry, professor
99 publications,  2 395 citations,  35 reviews
h-index: 25
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Asymmetric metal complex catalysis
Catalysis
Medicinal Chemistry
Organic Chemistry
Total synthesis
1 citation
Smirnov Ivan
5 publications,  9 citations
h-index: 3
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
National Research University Higher School of Economics
National Research University Higher School of Economics
Research interests
Catalysis
Data analysis
Machine learning
Organic Chemistry
Organometallic Chemistry
1 citation
Kagilev Alexey
33 publications,  391 citations
h-index: 11
Kazan Federal University
Kazan Federal University
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
Kazan Scientific Center of the Russian Academy of Sciences
Kazan Scientific Center of the Russian Academy of Sciences

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GOST Copy
Osipova E. S. et al. Fac-to-mer isomerization triggers hydride transfer from Mn(i) complex fac-[(dppm)Mn(CO)3H] // Chemical Communications. 2022. Vol. 58. No. 32. pp. 5017-5020.
GOST all authors (up to 50) Copy
Osipova E. S., Osipova E. Y., Gulyaeva E. S., Kireev N. V., Kovalenko S. A., Bijani C., Canac Y., Valyaev D. A., Filippov O. A., Belkova N. V., Shubina E. S. Fac-to-mer isomerization triggers hydride transfer from Mn(i) complex fac-[(dppm)Mn(CO)3H] // Chemical Communications. 2022. Vol. 58. No. 32. pp. 5017-5020.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/d2cc00999d
UR - https://xlink.rsc.org/?DOI=D2CC00999D
TI - Fac-to-mer isomerization triggers hydride transfer from Mn(i) complex fac-[(dppm)Mn(CO)3H]
T2 - Chemical Communications
AU - Osipova, Elena S
AU - Osipova, Elena Y.
AU - Gulyaeva, Ekaterina S
AU - Kireev, Nikolay V
AU - Kovalenko, Sergey A
AU - Bijani, Christian
AU - Canac, Yves
AU - Valyaev, D. A.
AU - Filippov, Oleg A.
AU - Belkova, Natalia V
AU - Shubina, Elena S.
PY - 2022
DA - 2022/03/23
PB - Royal Society of Chemistry (RSC)
SP - 5017-5020
IS - 32
VL - 58
PMID - 35373227
SN - 1359-7345
SN - 1364-548X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Osipova,
author = {Elena S Osipova and Elena Y. Osipova and Ekaterina S Gulyaeva and Nikolay V Kireev and Sergey A Kovalenko and Christian Bijani and Yves Canac and D. A. Valyaev and Oleg A. Filippov and Natalia V Belkova and Elena S. Shubina},
title = {Fac-to-mer isomerization triggers hydride transfer from Mn(i) complex fac-[(dppm)Mn(CO)3H]},
journal = {Chemical Communications},
year = {2022},
volume = {58},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://xlink.rsc.org/?DOI=D2CC00999D},
number = {32},
pages = {5017--5020},
doi = {10.1039/d2cc00999d}
}
MLA
Cite this
MLA Copy
Osipova, Elena S., et al. “Fac-to-mer isomerization triggers hydride transfer from Mn(i) complex fac-[(dppm)Mn(CO)3H].” Chemical Communications, vol. 58, no. 32, Mar. 2022, pp. 5017-5020. https://xlink.rsc.org/?DOI=D2CC00999D.