Open Access
Rh-catalyzed regio-switchable cross-coupling of gem-difluorinated cyclopropanes with allylboronates to structurally diverse fluorinated dienes
Publication type: Journal Article
Publication date: 2022-10-05
scimago Q1
wos Q1
SJR: 2.138
CiteScore: 12.6
Impact factor: 7.4
ISSN: 20416520, 20416539
PubMed ID:
36382270
General Chemistry
Abstract
The control of linear/branched selectivity is one of the major focuses in transition-metal catalyzed allyl–allyl cross-coupling reactions, in which bond connection occurs at the terminal site of both the allyl fragments forming different types of 1,5-dienes. Herein, terminal/internal regioselectivity is investigated and found to be switchable in allyl–allyl cross-coupling reactions between gem-difluorinated cyclopropanes and allylboronates. The controlled terminal/internal regioselectivity arises from the fine-tuning of the rhodium catalytic system. Fluorinated 1,3-dienes, 1,4-dienes and 1,5-dienes are therefore produced in good yields with respectively isomerized terminal, internal, and terminal regioselectivity.
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Metrics
39
Total citations:
39
Citations from 2025:
8
(20.51%)
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GOST
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Zeng Y. et al. Rh-catalyzed regio-switchable cross-coupling of gem-difluorinated cyclopropanes with allylboronates to structurally diverse fluorinated dienes // Chemical Science. 2022. Vol. 13. No. 42. pp. 12419-12425.
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Zeng Y., Yang H., Du J., HUANG Q., Huang G., Xia Y. Rh-catalyzed regio-switchable cross-coupling of gem-difluorinated cyclopropanes with allylboronates to structurally diverse fluorinated dienes // Chemical Science. 2022. Vol. 13. No. 42. pp. 12419-12425.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d2sc04118a
UR - https://xlink.rsc.org/?DOI=D2SC04118A
TI - Rh-catalyzed regio-switchable cross-coupling of gem-difluorinated cyclopropanes with allylboronates to structurally diverse fluorinated dienes
T2 - Chemical Science
AU - Zeng, Yaxin
AU - Yang, Hui
AU - Du, Jiayi
AU - HUANG, QIN
AU - Huang, Guoliang
AU - Xia, Ying
PY - 2022
DA - 2022/10/05
PB - Royal Society of Chemistry (RSC)
SP - 12419-12425
IS - 42
VL - 13
PMID - 36382270
SN - 2041-6520
SN - 2041-6539
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Zeng,
author = {Yaxin Zeng and Hui Yang and Jiayi Du and QIN HUANG and Guoliang Huang and Ying Xia},
title = {Rh-catalyzed regio-switchable cross-coupling of gem-difluorinated cyclopropanes with allylboronates to structurally diverse fluorinated dienes},
journal = {Chemical Science},
year = {2022},
volume = {13},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=D2SC04118A},
number = {42},
pages = {12419--12425},
doi = {10.1039/d2sc04118a}
}
Cite this
MLA
Copy
Zeng, Yaxin, et al. “Rh-catalyzed regio-switchable cross-coupling of gem-difluorinated cyclopropanes with allylboronates to structurally diverse fluorinated dienes.” Chemical Science, vol. 13, no. 42, Oct. 2022, pp. 12419-12425. https://xlink.rsc.org/?DOI=D2SC04118A.