Royal Society of Chemistry (RSC)
Dalton Transactions
,  volume 54 ,  issue 14 ,  pages 5655-5658

Planar chiral arene ruthenium complexes derived from R-carvone

Publication type: Journal Article
Publication date: 2025-03-11
Royal Society of Chemistry (RSC)
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
Abstract
Natural R-carvone was converted into chiral 1-aryl-2-methyl-5-isopropyl-cyclohexadienes using a cross-coupling reaction as a key step. These dienes react with RuCl3 to give planar-chiral complexes [(arene)RuCl2]2 in 70–75% yields. Complex [(1-Ph-2-Me-5-iPr-C6H3)RuCl2]2, a chiral analogue of the classical catalyst [(cymene)RuCl2]2, promotes C–H activation of N-methoxy-benzamide and intramolecular insertion of a diazo compound into a C–H bond, but gives products with low stereoselectivity.
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Boym M. A. et al. Planar chiral arene ruthenium complexes derived from R-carvone // Dalton Transactions. 2025. Vol. 54. No. 14. pp. 5655-5658.
GOST all authors (up to 50) Copy
Boym M. A., Pototskiy R. A., Podyacheva E. S., Muratov D. V., Nelyubina Y. V., Perekalin D. S. Planar chiral arene ruthenium complexes derived from R-carvone // Dalton Transactions. 2025. Vol. 54. No. 14. pp. 5655-5658.
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TY - JOUR
DO - 10.1039/d5dt00344j
UR - https://xlink.rsc.org/?DOI=D5DT00344J
TI - Planar chiral arene ruthenium complexes derived from R-carvone
T2 - Dalton Transactions
AU - Boym, Mikhail A
AU - Pototskiy, Roman A
AU - Podyacheva, Evgeniya S.
AU - Muratov, Dmitry V
AU - Nelyubina, Yulia V.
AU - Perekalin, Dmitry S
PY - 2025
DA - 2025/03/11
PB - Royal Society of Chemistry (RSC)
SP - 5655-5658
IS - 14
VL - 54
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2025_Boym,
author = {Mikhail A Boym and Roman A Pototskiy and Evgeniya S. Podyacheva and Dmitry V Muratov and Yulia V. Nelyubina and Dmitry S Perekalin},
title = {Planar chiral arene ruthenium complexes derived from R-carvone},
journal = {Dalton Transactions},
year = {2025},
volume = {54},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://xlink.rsc.org/?DOI=D5DT00344J},
number = {14},
pages = {5655--5658},
doi = {10.1039/d5dt00344j}
}
MLA
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Boym, Mikhail A., et al. “Planar chiral arene ruthenium complexes derived from R-carvone.” Dalton Transactions, vol. 54, no. 14, Mar. 2025, pp. 5655-5658. https://xlink.rsc.org/?DOI=D5DT00344J.